Materials Data on V4Bi3 by Materials Project
Abstract
V4Bi3 is Magnesium tetraboride-like structured and crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. there are five inequivalent V sites. In the first V site, V is bonded in a 9-coordinate geometry to four V and five Bi atoms. There are a spread of V–V bond distances ranging from 2.39–2.59 Å. There are a spread of V–Bi bond distances ranging from 2.95–3.13 Å. In the second V site, V is bonded in a 6-coordinate geometry to one V and six Bi atoms. The V–V bond length is 2.79 Å. There are a spread of V–Bi bond distances ranging from 2.82–2.90 Å. In the third V site, V is bonded in a 7-coordinate geometry to four V and five Bi atoms. Both V–V bond lengths are 2.91 Å. There are a spread of V–Bi bond distances ranging from 2.86–2.95 Å. In the fourth V site, V is bonded in a 8-coordinate geometry to two equivalent V and six Bi atoms. There are two shorter (2.76 Å) and four longer (2.90 Å) V–Bi bond lengths. In the fifth V site, V is bonded in a 12-coordinate geometry to eight V and four Bi atoms. There are two shorter (2.76more »
- Authors:
- Publication Date:
- Other Number(s):
- mp-1120821
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; V4Bi3; Bi-V
- OSTI Identifier:
- 1739320
- DOI:
- https://doi.org/10.17188/1739320
Citation Formats
The Materials Project. Materials Data on V4Bi3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1739320.
The Materials Project. Materials Data on V4Bi3 by Materials Project. United States. doi:https://doi.org/10.17188/1739320
The Materials Project. 2020.
"Materials Data on V4Bi3 by Materials Project". United States. doi:https://doi.org/10.17188/1739320. https://www.osti.gov/servlets/purl/1739320. Pub date:Tue May 05 00:00:00 EDT 2020
@article{osti_1739320,
title = {Materials Data on V4Bi3 by Materials Project},
author = {The Materials Project},
abstractNote = {V4Bi3 is Magnesium tetraboride-like structured and crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. there are five inequivalent V sites. In the first V site, V is bonded in a 9-coordinate geometry to four V and five Bi atoms. There are a spread of V–V bond distances ranging from 2.39–2.59 Å. There are a spread of V–Bi bond distances ranging from 2.95–3.13 Å. In the second V site, V is bonded in a 6-coordinate geometry to one V and six Bi atoms. The V–V bond length is 2.79 Å. There are a spread of V–Bi bond distances ranging from 2.82–2.90 Å. In the third V site, V is bonded in a 7-coordinate geometry to four V and five Bi atoms. Both V–V bond lengths are 2.91 Å. There are a spread of V–Bi bond distances ranging from 2.86–2.95 Å. In the fourth V site, V is bonded in a 8-coordinate geometry to two equivalent V and six Bi atoms. There are two shorter (2.76 Å) and four longer (2.90 Å) V–Bi bond lengths. In the fifth V site, V is bonded in a 12-coordinate geometry to eight V and four Bi atoms. There are two shorter (2.76 Å) and two longer (2.88 Å) V–Bi bond lengths. There are three inequivalent Bi sites. In the first Bi site, Bi is bonded in a 8-coordinate geometry to eight V atoms. In the second Bi site, Bi is bonded in a 6-coordinate geometry to six V atoms. In the third Bi site, Bi is bonded in a 7-coordinate geometry to seven V atoms.},
doi = {10.17188/1739320},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}