U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Mn4BiSb3 by Materials Project
Abstract
Mn4Sb3Bi crystallizes in the orthorhombic Pmm2 space group. The structure is three-dimensional and consists of one bismuth molecule and one Mn4Sb3 framework. In the Mn4Sb3 framework, there are two inequivalent Mn2+ sites. In the first Mn2+ site, Mn2+ is bonded in a distorted see-saw-like geometry to four Sb3- atoms. There are a spread of Mn–Sb bond distances ranging from 2.74–2.81 Å. In the second Mn2+ site, Mn2+ is bonded to five Sb3- atoms to form a mixture of distorted edge, corner, and face-sharing MnSb5 square pyramids. There are a spread of Mn–Sb bond distances ranging from 2.74–2.80 Å. There are three inequivalent Sb3- sites. In the first Sb3- site, Sb3- is bonded in a 6-coordinate geometry to six Mn2+ atoms. In the second Sb3- site, Sb3- is bonded in a 6-coordinate geometry to six Mn2+ atoms. In the third Sb3- site, Sb3- is bonded in a 6-coordinate geometry to six Mn2+ atoms.
- Publication Date:
- Other Number(s):
- mp-1221739
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Bi-Mn-Sb; Mn4BiSb3; crystal structure
- OSTI Identifier:
- 1738845
- DOI:
- https://doi.org/10.17188/1738845
Citation Formats
Materials Data on Mn4BiSb3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1738845.
Materials Data on Mn4BiSb3 by Materials Project. United States. doi:https://doi.org/10.17188/1738845
2020.
"Materials Data on Mn4BiSb3 by Materials Project". United States. doi:https://doi.org/10.17188/1738845. https://www.osti.gov/servlets/purl/1738845. Pub date:Fri Jun 05 00:00:00 EDT 2020
@article{osti_1738845,
title = {Materials Data on Mn4BiSb3 by Materials Project},
abstractNote = {Mn4Sb3Bi crystallizes in the orthorhombic Pmm2 space group. The structure is three-dimensional and consists of one bismuth molecule and one Mn4Sb3 framework. In the Mn4Sb3 framework, there are two inequivalent Mn2+ sites. In the first Mn2+ site, Mn2+ is bonded in a distorted see-saw-like geometry to four Sb3- atoms. There are a spread of Mn–Sb bond distances ranging from 2.74–2.81 Å. In the second Mn2+ site, Mn2+ is bonded to five Sb3- atoms to form a mixture of distorted edge, corner, and face-sharing MnSb5 square pyramids. There are a spread of Mn–Sb bond distances ranging from 2.74–2.80 Å. There are three inequivalent Sb3- sites. In the first Sb3- site, Sb3- is bonded in a 6-coordinate geometry to six Mn2+ atoms. In the second Sb3- site, Sb3- is bonded in a 6-coordinate geometry to six Mn2+ atoms. In the third Sb3- site, Sb3- is bonded in a 6-coordinate geometry to six Mn2+ atoms.},
doi = {10.17188/1738845},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {6}
}