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Title: Materials Data on Mn4BiSb3 by Materials Project

Abstract

Mn4Sb3Bi crystallizes in the orthorhombic Pmm2 space group. The structure is three-dimensional and consists of one bismuth molecule and one Mn4Sb3 framework. In the Mn4Sb3 framework, there are two inequivalent Mn2+ sites. In the first Mn2+ site, Mn2+ is bonded in a distorted see-saw-like geometry to four Sb3- atoms. There are a spread of Mn–Sb bond distances ranging from 2.74–2.81 Å. In the second Mn2+ site, Mn2+ is bonded to five Sb3- atoms to form a mixture of distorted edge, corner, and face-sharing MnSb5 square pyramids. There are a spread of Mn–Sb bond distances ranging from 2.74–2.80 Å. There are three inequivalent Sb3- sites. In the first Sb3- site, Sb3- is bonded in a 6-coordinate geometry to six Mn2+ atoms. In the second Sb3- site, Sb3- is bonded in a 6-coordinate geometry to six Mn2+ atoms. In the third Sb3- site, Sb3- is bonded in a 6-coordinate geometry to six Mn2+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-1221739
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Mn4BiSb3; Bi-Mn-Sb
OSTI Identifier:
1738845
DOI:
https://doi.org/10.17188/1738845

Citation Formats

The Materials Project. Materials Data on Mn4BiSb3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1738845.
The Materials Project. Materials Data on Mn4BiSb3 by Materials Project. United States. doi:https://doi.org/10.17188/1738845
The Materials Project. 2020. "Materials Data on Mn4BiSb3 by Materials Project". United States. doi:https://doi.org/10.17188/1738845. https://www.osti.gov/servlets/purl/1738845. Pub date:Fri Jun 05 00:00:00 EDT 2020
@article{osti_1738845,
title = {Materials Data on Mn4BiSb3 by Materials Project},
author = {The Materials Project},
abstractNote = {Mn4Sb3Bi crystallizes in the orthorhombic Pmm2 space group. The structure is three-dimensional and consists of one bismuth molecule and one Mn4Sb3 framework. In the Mn4Sb3 framework, there are two inequivalent Mn2+ sites. In the first Mn2+ site, Mn2+ is bonded in a distorted see-saw-like geometry to four Sb3- atoms. There are a spread of Mn–Sb bond distances ranging from 2.74–2.81 Å. In the second Mn2+ site, Mn2+ is bonded to five Sb3- atoms to form a mixture of distorted edge, corner, and face-sharing MnSb5 square pyramids. There are a spread of Mn–Sb bond distances ranging from 2.74–2.80 Å. There are three inequivalent Sb3- sites. In the first Sb3- site, Sb3- is bonded in a 6-coordinate geometry to six Mn2+ atoms. In the second Sb3- site, Sb3- is bonded in a 6-coordinate geometry to six Mn2+ atoms. In the third Sb3- site, Sb3- is bonded in a 6-coordinate geometry to six Mn2+ atoms.},
doi = {10.17188/1738845},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {6}
}