DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on LaN(ClO)4 by Materials Project

Abstract

La(OCl2)2NO2 crystallizes in the orthorhombic P2_12_12 space group. The structure is one-dimensional and consists of two nitrous acid molecules and two La(OCl2)2 ribbons oriented in the (1, 0, 0) direction. In each La(OCl2)2 ribbon, La is bonded in a 8-coordinate geometry to four equivalent O and two equivalent Cl atoms. All La–O bond lengths are 2.44 Å. Both La–Cl bond lengths are 2.82 Å. O is bonded in a distorted T-shaped geometry to two equivalent La and one Cl atom. The O–Cl bond length is 1.68 Å. There are two inequivalent Cl sites. In the first Cl site, Cl is bonded in a single-bond geometry to one O atom. In the second Cl site, Cl is bonded in a single-bond geometry to one La atom.

Authors:
Publication Date:
Other Number(s):
mp-1212058
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; LaN(ClO)4; Cl-La-N-O
OSTI Identifier:
1738598
DOI:
https://doi.org/10.17188/1738598

Citation Formats

The Materials Project. Materials Data on LaN(ClO)4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1738598.
The Materials Project. Materials Data on LaN(ClO)4 by Materials Project. United States. doi:https://doi.org/10.17188/1738598
The Materials Project. 2020. "Materials Data on LaN(ClO)4 by Materials Project". United States. doi:https://doi.org/10.17188/1738598. https://www.osti.gov/servlets/purl/1738598. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1738598,
title = {Materials Data on LaN(ClO)4 by Materials Project},
author = {The Materials Project},
abstractNote = {La(OCl2)2NO2 crystallizes in the orthorhombic P2_12_12 space group. The structure is one-dimensional and consists of two nitrous acid molecules and two La(OCl2)2 ribbons oriented in the (1, 0, 0) direction. In each La(OCl2)2 ribbon, La is bonded in a 8-coordinate geometry to four equivalent O and two equivalent Cl atoms. All La–O bond lengths are 2.44 Å. Both La–Cl bond lengths are 2.82 Å. O is bonded in a distorted T-shaped geometry to two equivalent La and one Cl atom. The O–Cl bond length is 1.68 Å. There are two inequivalent Cl sites. In the first Cl site, Cl is bonded in a single-bond geometry to one O atom. In the second Cl site, Cl is bonded in a single-bond geometry to one La atom.},
doi = {10.17188/1738598},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}