U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on SbS4N3 by Materials Project
Abstract
SbN3S4 crystallizes in the triclinic P1 space group. The structure is one-dimensional and consists of one SbN3S4 ribbon oriented in the (0, 1, 0) direction. Sb3+ is bonded in a 2-coordinate geometry to two S2- atoms. There are one shorter (2.55 Å) and one longer (2.62 Å) Sb–S bond lengths. There are three inequivalent N+1.67+ sites. In the first N+1.67+ site, N+1.67+ is bonded in a bent 120 degrees geometry to two S2- atoms. There is one shorter (1.21 Å) and one longer (2.09 Å) N–S bond length. In the second N+1.67+ site, N+1.67+ is bonded in a distorted single-bond geometry to two S2- atoms. There is one shorter (1.34 Å) and one longer (2.52 Å) N–S bond length. In the third N+1.67+ site, N+1.67+ is bonded in a single-bond geometry to two S2- atoms. There are one shorter (1.60 Å) and one longer (2.66 Å) N–S bond lengths. There are four inequivalent S2- sites. In the first S2- site, S2- is bonded in a distorted water-like geometry to one Sb3+ and two N+1.67+ atoms. In the second S2- site, S2- is bonded in a single-bond geometry to one Sb3+ atom. In the third S2- site, S2- is bonded inmore »
- Publication Date:
- Other Number(s):
- mp-1179558
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; N-S-Sb; SbS4N3; crystal structure
- OSTI Identifier:
- 1738091
- DOI:
- https://doi.org/10.17188/1738091
Citation Formats
Materials Data on SbS4N3 by Materials Project. United States: N. p., 2019.
Web. doi:10.17188/1738091.
Materials Data on SbS4N3 by Materials Project. United States. doi:https://doi.org/10.17188/1738091
2019.
"Materials Data on SbS4N3 by Materials Project". United States. doi:https://doi.org/10.17188/1738091. https://www.osti.gov/servlets/purl/1738091. Pub date:Thu Jan 10 23:00:00 EST 2019
@article{osti_1738091,
title = {Materials Data on SbS4N3 by Materials Project},
abstractNote = {SbN3S4 crystallizes in the triclinic P1 space group. The structure is one-dimensional and consists of one SbN3S4 ribbon oriented in the (0, 1, 0) direction. Sb3+ is bonded in a 2-coordinate geometry to two S2- atoms. There are one shorter (2.55 Å) and one longer (2.62 Å) Sb–S bond lengths. There are three inequivalent N+1.67+ sites. In the first N+1.67+ site, N+1.67+ is bonded in a bent 120 degrees geometry to two S2- atoms. There is one shorter (1.21 Å) and one longer (2.09 Å) N–S bond length. In the second N+1.67+ site, N+1.67+ is bonded in a distorted single-bond geometry to two S2- atoms. There is one shorter (1.34 Å) and one longer (2.52 Å) N–S bond length. In the third N+1.67+ site, N+1.67+ is bonded in a single-bond geometry to two S2- atoms. There are one shorter (1.60 Å) and one longer (2.66 Å) N–S bond lengths. There are four inequivalent S2- sites. In the first S2- site, S2- is bonded in a distorted water-like geometry to one Sb3+ and two N+1.67+ atoms. In the second S2- site, S2- is bonded in a single-bond geometry to one Sb3+ atom. In the third S2- site, S2- is bonded in a 2-coordinate geometry to three N+1.67+ atoms. In the fourth S2- site, S2- is bonded in a single-bond geometry to one N+1.67+ atom.},
doi = {10.17188/1738091},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}