U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Nd2CdSb4 by Materials Project
Abstract
Nd2CdSb4 crystallizes in the tetragonal P-4m2 space group. The structure is three-dimensional. Nd3+ is bonded in a 8-coordinate geometry to eight Sb2- atoms. There are four shorter (3.25 Å) and four longer (3.35 Å) Nd–Sb bond lengths. Cd2+ is bonded to four equivalent Sb2- atoms to form corner-sharing CdSb4 tetrahedra. All Cd–Sb bond lengths are 2.89 Å. There are two inequivalent Sb2- sites. In the first Sb2- site, Sb2- is bonded to four equivalent Nd3+ and two equivalent Cd2+ atoms to form a mixture of distorted face, edge, and corner-sharing SbNd4Cd2 pentagonal pyramids. In the second Sb2- site, Sb2- is bonded in a 8-coordinate geometry to four equivalent Nd3+ and four equivalent Sb2- atoms. All Sb–Sb bond lengths are 3.10 Å.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1220339
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Nd2CdSb4; Cd-Nd-Sb
- OSTI Identifier:
- 1736350
- DOI:
- https://doi.org/10.17188/1736350
Citation Formats
The Materials Project. Materials Data on Nd2CdSb4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1736350.
The Materials Project. Materials Data on Nd2CdSb4 by Materials Project. United States. doi:https://doi.org/10.17188/1736350
The Materials Project. 2020.
"Materials Data on Nd2CdSb4 by Materials Project". United States. doi:https://doi.org/10.17188/1736350. https://www.osti.gov/servlets/purl/1736350. Pub date:Sun May 03 00:00:00 EDT 2020
@article{osti_1736350,
title = {Materials Data on Nd2CdSb4 by Materials Project},
author = {The Materials Project},
abstractNote = {Nd2CdSb4 crystallizes in the tetragonal P-4m2 space group. The structure is three-dimensional. Nd3+ is bonded in a 8-coordinate geometry to eight Sb2- atoms. There are four shorter (3.25 Å) and four longer (3.35 Å) Nd–Sb bond lengths. Cd2+ is bonded to four equivalent Sb2- atoms to form corner-sharing CdSb4 tetrahedra. All Cd–Sb bond lengths are 2.89 Å. There are two inequivalent Sb2- sites. In the first Sb2- site, Sb2- is bonded to four equivalent Nd3+ and two equivalent Cd2+ atoms to form a mixture of distorted face, edge, and corner-sharing SbNd4Cd2 pentagonal pyramids. In the second Sb2- site, Sb2- is bonded in a 8-coordinate geometry to four equivalent Nd3+ and four equivalent Sb2- atoms. All Sb–Sb bond lengths are 3.10 Å.},
doi = {10.17188/1736350},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}