Materials Data on VPt3 by Materials Project
Abstract
Pt3V crystallizes in the trigonal R-3m space group. The structure is three-dimensional. V2+ is bonded in a distorted hexagonal planar geometry to six equivalent Pt+0.67- atoms. All V–Pt bond lengths are 2.64 Å. There are four inequivalent Pt+0.67- sites. In the first Pt+0.67- site, Pt+0.67- is bonded in a 12-coordinate geometry to three equivalent V2+ and three equivalent Pt+0.67- atoms. All Pt–Pt bond lengths are 2.92 Å. In the second Pt+0.67- site, Pt+0.67- is bonded to twelve Pt+0.67- atoms to form a mixture of edge, face, and corner-sharing PtPt12 cuboctahedra. All Pt–Pt bond lengths are 2.77 Å. In the third Pt+0.67- site, Pt+0.67- is bonded in a 12-coordinate geometry to three equivalent V2+ and three equivalent Pt+0.67- atoms. All Pt–V bond lengths are 2.64 Å. All Pt–Pt bond lengths are 2.92 Å. In the fourth Pt+0.67- site, Pt+0.67- is bonded to sixteen Pt+0.67- atoms to form a mixture of edge, face, and corner-sharing PtPt16 cuboctahedra. There are a spread of Pt–Pt bond distances ranging from 2.77–5.54 Å.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1216270
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; VPt3; Pt-V
- OSTI Identifier:
- 1734030
- DOI:
- https://doi.org/10.17188/1734030
Citation Formats
The Materials Project. Materials Data on VPt3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1734030.
The Materials Project. Materials Data on VPt3 by Materials Project. United States. doi:https://doi.org/10.17188/1734030
The Materials Project. 2020.
"Materials Data on VPt3 by Materials Project". United States. doi:https://doi.org/10.17188/1734030. https://www.osti.gov/servlets/purl/1734030. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1734030,
title = {Materials Data on VPt3 by Materials Project},
author = {The Materials Project},
abstractNote = {Pt3V crystallizes in the trigonal R-3m space group. The structure is three-dimensional. V2+ is bonded in a distorted hexagonal planar geometry to six equivalent Pt+0.67- atoms. All V–Pt bond lengths are 2.64 Å. There are four inequivalent Pt+0.67- sites. In the first Pt+0.67- site, Pt+0.67- is bonded in a 12-coordinate geometry to three equivalent V2+ and three equivalent Pt+0.67- atoms. All Pt–Pt bond lengths are 2.92 Å. In the second Pt+0.67- site, Pt+0.67- is bonded to twelve Pt+0.67- atoms to form a mixture of edge, face, and corner-sharing PtPt12 cuboctahedra. All Pt–Pt bond lengths are 2.77 Å. In the third Pt+0.67- site, Pt+0.67- is bonded in a 12-coordinate geometry to three equivalent V2+ and three equivalent Pt+0.67- atoms. All Pt–V bond lengths are 2.64 Å. All Pt–Pt bond lengths are 2.92 Å. In the fourth Pt+0.67- site, Pt+0.67- is bonded to sixteen Pt+0.67- atoms to form a mixture of edge, face, and corner-sharing PtPt16 cuboctahedra. There are a spread of Pt–Pt bond distances ranging from 2.77–5.54 Å.},
doi = {10.17188/1734030},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat May 02 00:00:00 EDT 2020},
month = {Sat May 02 00:00:00 EDT 2020}
}