U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on NaH24Ru(C2N5)4 by Materials Project
Abstract
NaRuN18(N(CH3)4)2 crystallizes in the cubic Pa-3 space group. The structure is three-dimensional and consists of eight tetramethylammonium molecules and one NaRuN18 framework. In the NaRuN18 framework, Na1+ is bonded in an octahedral geometry to six equivalent N3- atoms. All Na–N bond lengths are 2.76 Å. Ru3+ is bonded in an octahedral geometry to six equivalent N3- atoms. All Ru–N bond lengths are 2.08 Å. There are three inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted bent 120 degrees geometry to one Ru3+ and one N3- atom. The N–N bond length is 1.20 Å. In the second N3- site, N3- is bonded in a linear geometry to two N3- atoms. The N–N bond length is 1.18 Å. In the third N3- site, N3- is bonded in a bent 150 degrees geometry to one Na1+ and one N3- atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1194938
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; NaH24Ru(C2N5)4; C-H-N-Na-Ru
- OSTI Identifier:
- 1732628
- DOI:
- https://doi.org/10.17188/1732628
Citation Formats
The Materials Project. Materials Data on NaH24Ru(C2N5)4 by Materials Project. United States: N. p., 2019.
Web. doi:10.17188/1732628.
The Materials Project. Materials Data on NaH24Ru(C2N5)4 by Materials Project. United States. doi:https://doi.org/10.17188/1732628
The Materials Project. 2019.
"Materials Data on NaH24Ru(C2N5)4 by Materials Project". United States. doi:https://doi.org/10.17188/1732628. https://www.osti.gov/servlets/purl/1732628. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1732628,
title = {Materials Data on NaH24Ru(C2N5)4 by Materials Project},
author = {The Materials Project},
abstractNote = {NaRuN18(N(CH3)4)2 crystallizes in the cubic Pa-3 space group. The structure is three-dimensional and consists of eight tetramethylammonium molecules and one NaRuN18 framework. In the NaRuN18 framework, Na1+ is bonded in an octahedral geometry to six equivalent N3- atoms. All Na–N bond lengths are 2.76 Å. Ru3+ is bonded in an octahedral geometry to six equivalent N3- atoms. All Ru–N bond lengths are 2.08 Å. There are three inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted bent 120 degrees geometry to one Ru3+ and one N3- atom. The N–N bond length is 1.20 Å. In the second N3- site, N3- is bonded in a linear geometry to two N3- atoms. The N–N bond length is 1.18 Å. In the third N3- site, N3- is bonded in a bent 150 degrees geometry to one Na1+ and one N3- atom.},
doi = {10.17188/1732628},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Jan 12 00:00:00 EST 2019},
month = {Sat Jan 12 00:00:00 EST 2019}
}