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Title: Materials Data on NaH24Ru(C2N5)4 by Materials Project

Abstract

NaRuN18(N(CH3)4)2 crystallizes in the cubic Pa-3 space group. The structure is three-dimensional and consists of eight tetramethylammonium molecules and one NaRuN18 framework. In the NaRuN18 framework, Na1+ is bonded in an octahedral geometry to six equivalent N3- atoms. All Na–N bond lengths are 2.76 Å. Ru3+ is bonded in an octahedral geometry to six equivalent N3- atoms. All Ru–N bond lengths are 2.08 Å. There are three inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted bent 120 degrees geometry to one Ru3+ and one N3- atom. The N–N bond length is 1.20 Å. In the second N3- site, N3- is bonded in a linear geometry to two N3- atoms. The N–N bond length is 1.18 Å. In the third N3- site, N3- is bonded in a bent 150 degrees geometry to one Na1+ and one N3- atom.

Authors:
Publication Date:
Other Number(s):
mp-1194938
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; NaH24Ru(C2N5)4; C-H-N-Na-Ru
OSTI Identifier:
1732628
DOI:
https://doi.org/10.17188/1732628

Citation Formats

The Materials Project. Materials Data on NaH24Ru(C2N5)4 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1732628.
The Materials Project. Materials Data on NaH24Ru(C2N5)4 by Materials Project. United States. doi:https://doi.org/10.17188/1732628
The Materials Project. 2019. "Materials Data on NaH24Ru(C2N5)4 by Materials Project". United States. doi:https://doi.org/10.17188/1732628. https://www.osti.gov/servlets/purl/1732628. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1732628,
title = {Materials Data on NaH24Ru(C2N5)4 by Materials Project},
author = {The Materials Project},
abstractNote = {NaRuN18(N(CH3)4)2 crystallizes in the cubic Pa-3 space group. The structure is three-dimensional and consists of eight tetramethylammonium molecules and one NaRuN18 framework. In the NaRuN18 framework, Na1+ is bonded in an octahedral geometry to six equivalent N3- atoms. All Na–N bond lengths are 2.76 Å. Ru3+ is bonded in an octahedral geometry to six equivalent N3- atoms. All Ru–N bond lengths are 2.08 Å. There are three inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted bent 120 degrees geometry to one Ru3+ and one N3- atom. The N–N bond length is 1.20 Å. In the second N3- site, N3- is bonded in a linear geometry to two N3- atoms. The N–N bond length is 1.18 Å. In the third N3- site, N3- is bonded in a bent 150 degrees geometry to one Na1+ and one N3- atom.},
doi = {10.17188/1732628},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}