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Title: Materials Data on NiSb2H12(O3F4)2 by Materials Project

Abstract

Ni(H2O)6(SbF4)2 crystallizes in the monoclinic P2_1/c space group. The structure is one-dimensional and consists of two nsvfpfuroxfzjs-uhfffaoysa-n molecules and two SbF4 ribbons oriented in the (0, 0, 1) direction. In each SbF4 ribbon, Sb3+ is bonded in a 5-coordinate geometry to five F1- atoms. There are a spread of Sb–F bond distances ranging from 1.96–2.68 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a 1-coordinate geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a distorted single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Sb3+ atoms. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom.

Authors:
Publication Date:
Other Number(s):
mp-1199397
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; NiSb2H12(O3F4)2; F-H-Ni-O-Sb
OSTI Identifier:
1732455
DOI:
https://doi.org/10.17188/1732455

Citation Formats

The Materials Project. Materials Data on NiSb2H12(O3F4)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1732455.
The Materials Project. Materials Data on NiSb2H12(O3F4)2 by Materials Project. United States. doi:https://doi.org/10.17188/1732455
The Materials Project. 2020. "Materials Data on NiSb2H12(O3F4)2 by Materials Project". United States. doi:https://doi.org/10.17188/1732455. https://www.osti.gov/servlets/purl/1732455. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1732455,
title = {Materials Data on NiSb2H12(O3F4)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Ni(H2O)6(SbF4)2 crystallizes in the monoclinic P2_1/c space group. The structure is one-dimensional and consists of two nsvfpfuroxfzjs-uhfffaoysa-n molecules and two SbF4 ribbons oriented in the (0, 0, 1) direction. In each SbF4 ribbon, Sb3+ is bonded in a 5-coordinate geometry to five F1- atoms. There are a spread of Sb–F bond distances ranging from 1.96–2.68 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a 1-coordinate geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a distorted single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Sb3+ atoms. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom.},
doi = {10.17188/1732455},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}