Materials Data on Co(BMo)3 by Materials Project
Abstract
Co(MoB)3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. there are two inequivalent Mo+2.33+ sites. In the first Mo+2.33+ site, Mo+2.33+ is bonded in a 6-coordinate geometry to six B3- atoms. There are a spread of Mo–B bond distances ranging from 2.31–2.53 Å. In the second Mo+2.33+ site, Mo+2.33+ is bonded in a 7-coordinate geometry to seven B3- atoms. There are a spread of Mo–B bond distances ranging from 2.35–2.50 Å. Co2+ is bonded in a square co-planar geometry to four equivalent B3- atoms. All Co–B bond lengths are 2.07 Å. There are two inequivalent B3- sites. In the first B3- site, B3- is bonded in a 9-coordinate geometry to six Mo+2.33+, two equivalent Co2+, and one B3- atom. The B–B bond length is 1.89 Å. In the second B3- site, B3- is bonded in a 9-coordinate geometry to seven Mo+2.33+ and two equivalent B3- atoms.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1104546
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Co(BMo)3; B-Co-Mo
- OSTI Identifier:
- 1732454
- DOI:
- https://doi.org/10.17188/1732454
Citation Formats
The Materials Project. Materials Data on Co(BMo)3 by Materials Project. United States: N. p., 2018.
Web. doi:10.17188/1732454.
The Materials Project. Materials Data on Co(BMo)3 by Materials Project. United States. doi:https://doi.org/10.17188/1732454
The Materials Project. 2018.
"Materials Data on Co(BMo)3 by Materials Project". United States. doi:https://doi.org/10.17188/1732454. https://www.osti.gov/servlets/purl/1732454. Pub date:Wed Jul 18 00:00:00 EDT 2018
@article{osti_1732454,
title = {Materials Data on Co(BMo)3 by Materials Project},
author = {The Materials Project},
abstractNote = {Co(MoB)3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. there are two inequivalent Mo+2.33+ sites. In the first Mo+2.33+ site, Mo+2.33+ is bonded in a 6-coordinate geometry to six B3- atoms. There are a spread of Mo–B bond distances ranging from 2.31–2.53 Å. In the second Mo+2.33+ site, Mo+2.33+ is bonded in a 7-coordinate geometry to seven B3- atoms. There are a spread of Mo–B bond distances ranging from 2.35–2.50 Å. Co2+ is bonded in a square co-planar geometry to four equivalent B3- atoms. All Co–B bond lengths are 2.07 Å. There are two inequivalent B3- sites. In the first B3- site, B3- is bonded in a 9-coordinate geometry to six Mo+2.33+, two equivalent Co2+, and one B3- atom. The B–B bond length is 1.89 Å. In the second B3- site, B3- is bonded in a 9-coordinate geometry to seven Mo+2.33+ and two equivalent B3- atoms.},
doi = {10.17188/1732454},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {7}
}