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Title: Materials Data on Rb2SeO4 by Materials Project

Abstract

Rb2SeO4 crystallizes in the monoclinic Cc space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 5-coordinate geometry to five O2- atoms. There are a spread of Rb–O bond distances ranging from 2.80–3.08 Å. In the second Rb1+ site, Rb1+ is bonded in a 5-coordinate geometry to five O2- atoms. There are a spread of Rb–O bond distances ranging from 2.75–3.27 Å. Se6+ is bonded in a water-like geometry to two O2- atoms. Both Se–O bond lengths are 1.71 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to two equivalent Rb1+ and one Se6+ atom. In the second O2- site, O2- is bonded in a 2-coordinate geometry to two Rb1+ and one Se6+ atom. In the third O2- site, O2- is bonded in a 4-coordinate geometry to three Rb1+ and one O2- atom. The O–O bond length is 1.36 Å. In the fourth O2- site, O2- is bonded to three Rb1+ and one O2- atom to form distorted corner-sharing ORb3O trigonal pyramids.

Authors:
Publication Date:
Other Number(s):
mp-1173599
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Rb2SeO4; O-Rb-Se
OSTI Identifier:
1732380
DOI:
https://doi.org/10.17188/1732380

Citation Formats

The Materials Project. Materials Data on Rb2SeO4 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1732380.
The Materials Project. Materials Data on Rb2SeO4 by Materials Project. United States. doi:https://doi.org/10.17188/1732380
The Materials Project. 2019. "Materials Data on Rb2SeO4 by Materials Project". United States. doi:https://doi.org/10.17188/1732380. https://www.osti.gov/servlets/purl/1732380. Pub date:Fri Jan 11 00:00:00 EST 2019
@article{osti_1732380,
title = {Materials Data on Rb2SeO4 by Materials Project},
author = {The Materials Project},
abstractNote = {Rb2SeO4 crystallizes in the monoclinic Cc space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 5-coordinate geometry to five O2- atoms. There are a spread of Rb–O bond distances ranging from 2.80–3.08 Å. In the second Rb1+ site, Rb1+ is bonded in a 5-coordinate geometry to five O2- atoms. There are a spread of Rb–O bond distances ranging from 2.75–3.27 Å. Se6+ is bonded in a water-like geometry to two O2- atoms. Both Se–O bond lengths are 1.71 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to two equivalent Rb1+ and one Se6+ atom. In the second O2- site, O2- is bonded in a 2-coordinate geometry to two Rb1+ and one Se6+ atom. In the third O2- site, O2- is bonded in a 4-coordinate geometry to three Rb1+ and one O2- atom. The O–O bond length is 1.36 Å. In the fourth O2- site, O2- is bonded to three Rb1+ and one O2- atom to form distorted corner-sharing ORb3O trigonal pyramids.},
doi = {10.17188/1732380},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}