Materials Data on AgN2ClO4 by Materials Project
Abstract
AgN2O4Cl crystallizes in the monoclinic P2/m space group. The structure is one-dimensional and consists of two AgN2O4Cl ribbons oriented in the (-1, 0, 1) and (1, 0, 1) directions. In one of the AgN2O4Cl ribbons, there are two inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a 2-coordinate geometry to two equivalent N4+ and two equivalent O2- atoms. Both Ag–N bond lengths are 2.10 Å. Both Ag–O bond lengths are 2.76 Å. In the second Ag1+ site, Ag1+ is bonded in a distorted rectangular see-saw-like geometry to two equivalent N4+ and two equivalent O2- atoms. Both Ag–N bond lengths are 2.15 Å. Both Ag–O bond lengths are 2.35 Å. There are two inequivalent N4+ sites. In the first N4+ site, N4+ is bonded in a single-bond geometry to one Ag1+ atom. In the second N4+ site, N4+ is bonded in a single-bond geometry to one Ag1+ atom. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 150 degrees geometry to one Ag1+ and one Cl1- atom. The O–Cl bond length is 1.50 Å. In the second O2- site, O2- is bonded in a single-bond geometry to one Cl1-more »
- Authors:
- Publication Date:
- Other Number(s):
- mp-1204763
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; AgN2ClO4; Ag-Cl-N-O
- OSTI Identifier:
- 1732375
- DOI:
- https://doi.org/10.17188/1732375
Citation Formats
The Materials Project. Materials Data on AgN2ClO4 by Materials Project. United States: N. p., 2019.
Web. doi:10.17188/1732375.
The Materials Project. Materials Data on AgN2ClO4 by Materials Project. United States. doi:https://doi.org/10.17188/1732375
The Materials Project. 2019.
"Materials Data on AgN2ClO4 by Materials Project". United States. doi:https://doi.org/10.17188/1732375. https://www.osti.gov/servlets/purl/1732375. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1732375,
title = {Materials Data on AgN2ClO4 by Materials Project},
author = {The Materials Project},
abstractNote = {AgN2O4Cl crystallizes in the monoclinic P2/m space group. The structure is one-dimensional and consists of two AgN2O4Cl ribbons oriented in the (-1, 0, 1) and (1, 0, 1) directions. In one of the AgN2O4Cl ribbons, there are two inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a 2-coordinate geometry to two equivalent N4+ and two equivalent O2- atoms. Both Ag–N bond lengths are 2.10 Å. Both Ag–O bond lengths are 2.76 Å. In the second Ag1+ site, Ag1+ is bonded in a distorted rectangular see-saw-like geometry to two equivalent N4+ and two equivalent O2- atoms. Both Ag–N bond lengths are 2.15 Å. Both Ag–O bond lengths are 2.35 Å. There are two inequivalent N4+ sites. In the first N4+ site, N4+ is bonded in a single-bond geometry to one Ag1+ atom. In the second N4+ site, N4+ is bonded in a single-bond geometry to one Ag1+ atom. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 150 degrees geometry to one Ag1+ and one Cl1- atom. The O–Cl bond length is 1.50 Å. In the second O2- site, O2- is bonded in a single-bond geometry to one Cl1- atom. The O–Cl bond length is 1.45 Å. In the third O2- site, O2- is bonded in a distorted single-bond geometry to one Ag1+ and one Cl1- atom. The O–Cl bond length is 1.46 Å. Cl1- is bonded in a tetrahedral geometry to four O2- atoms. In one of the AgN2O4Cl ribbons, there are two inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a square co-planar geometry to two equivalent N4+ and two equivalent O2- atoms. Both Ag–N bond lengths are 2.15 Å. Both Ag–O bond lengths are 2.46 Å. In the second Ag1+ site, Ag1+ is bonded in a square co-planar geometry to two equivalent N4+ and two equivalent O2- atoms. Both Ag–N bond lengths are 2.14 Å. Both Ag–O bond lengths are 2.37 Å. There are two inequivalent N4+ sites. In the first N4+ site, N4+ is bonded in a single-bond geometry to one Ag1+ atom. In the second N4+ site, N4+ is bonded in a single-bond geometry to one Ag1+ atom. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Cl1- atom. The O–Cl bond length is 1.44 Å. In the second O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Ag1+ and one Cl1- atom. The O–Cl bond length is 1.50 Å. In the third O2- site, O2- is bonded in a bent 150 degrees geometry to one Ag1+ and one Cl1- atom. The O–Cl bond length is 1.49 Å. Cl1- is bonded in a tetrahedral geometry to four O2- atoms.},
doi = {10.17188/1732375},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}