U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Zn2H18Cl4O9 by Materials Project
Abstract
Zn(H2O)6ZnCl4(H2O)3 is alpha Pu-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of twelve water molecules, four ZnCl4 clusters, and four zinc hexahydrate molecules. In each ZnCl4 cluster, Zn2+ is bonded in a tetrahedral geometry to four Cl1- atoms. There are a spread of Zn–Cl bond distances ranging from 2.28–2.31 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom.
- Publication Date:
- Other Number(s):
- mp-1202834
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Cl-H-O-Zn; Zn2H18Cl4O9; crystal structure
- OSTI Identifier:
- 1732307
- DOI:
- https://doi.org/10.17188/1732307
Citation Formats
Materials Data on Zn2H18Cl4O9 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1732307.
Materials Data on Zn2H18Cl4O9 by Materials Project. United States. doi:https://doi.org/10.17188/1732307
2020.
"Materials Data on Zn2H18Cl4O9 by Materials Project". United States. doi:https://doi.org/10.17188/1732307. https://www.osti.gov/servlets/purl/1732307. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1732307,
title = {Materials Data on Zn2H18Cl4O9 by Materials Project},
abstractNote = {Zn(H2O)6ZnCl4(H2O)3 is alpha Pu-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of twelve water molecules, four ZnCl4 clusters, and four zinc hexahydrate molecules. In each ZnCl4 cluster, Zn2+ is bonded in a tetrahedral geometry to four Cl1- atoms. There are a spread of Zn–Cl bond distances ranging from 2.28–2.31 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom.},
doi = {10.17188/1732307},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}