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Title: Materials Data on SCl4 by Materials Project

Abstract

SCl4 crystallizes in the cubic P-43n space group. The structure is zero-dimensional and consists of eight SCl4 clusters. S4+ is bonded to six Cl1- atoms to form distorted edge-sharing SCl6 octahedra. There are three shorter (2.09 Å) and three longer (2.78 Å) S–Cl bond lengths. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one S4+ atom. In the second Cl1- site, Cl1- is bonded in a 3-coordinate geometry to three equivalent S4+ atoms.

Publication Date:
Other Number(s):
mp-1210452
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; SCl4; Cl-S
OSTI Identifier:
1729597
DOI:
https://doi.org/10.17188/1729597

Citation Formats

The Materials Project. Materials Data on SCl4 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1729597.
The Materials Project. Materials Data on SCl4 by Materials Project. United States. doi:https://doi.org/10.17188/1729597
The Materials Project. 2019. "Materials Data on SCl4 by Materials Project". United States. doi:https://doi.org/10.17188/1729597. https://www.osti.gov/servlets/purl/1729597. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1729597,
title = {Materials Data on SCl4 by Materials Project},
author = {The Materials Project},
abstractNote = {SCl4 crystallizes in the cubic P-43n space group. The structure is zero-dimensional and consists of eight SCl4 clusters. S4+ is bonded to six Cl1- atoms to form distorted edge-sharing SCl6 octahedra. There are three shorter (2.09 Å) and three longer (2.78 Å) S–Cl bond lengths. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one S4+ atom. In the second Cl1- site, Cl1- is bonded in a 3-coordinate geometry to three equivalent S4+ atoms.},
doi = {10.17188/1729597},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}