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Title: Materials Data on Ce4SiRh12 by Materials Project

Abstract

Ce4Rh12Si crystallizes in the cubic Im-3m space group. The structure is three-dimensional. Ce is bonded to twelve Rh atoms to form CeRh12 cuboctahedra that share corners with twelve equivalent CeRh12 cuboctahedra, faces with six equivalent CeRh12 cuboctahedra, and faces with two equivalent SiRh6 octahedra. There are six shorter (2.94 Å) and six longer (2.95 Å) Ce–Rh bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded in a distorted square co-planar geometry to four equivalent Ce atoms. In the second Rh site, Rh is bonded in a 5-coordinate geometry to four equivalent Ce and one Si atom. The Rh–Si bond length is 2.32 Å. Si is bonded to six equivalent Rh atoms to form SiRh6 octahedra that share faces with eight equivalent CeRh12 cuboctahedra.

Publication Date:
Other Number(s):
mp-1190081
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ce4SiRh12; Ce-Rh-Si
OSTI Identifier:
1729406
DOI:
https://doi.org/10.17188/1729406

Citation Formats

The Materials Project. Materials Data on Ce4SiRh12 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1729406.
The Materials Project. Materials Data on Ce4SiRh12 by Materials Project. United States. doi:https://doi.org/10.17188/1729406
The Materials Project. 2020. "Materials Data on Ce4SiRh12 by Materials Project". United States. doi:https://doi.org/10.17188/1729406. https://www.osti.gov/servlets/purl/1729406. Pub date:Sun May 03 00:00:00 EDT 2020
@article{osti_1729406,
title = {Materials Data on Ce4SiRh12 by Materials Project},
author = {The Materials Project},
abstractNote = {Ce4Rh12Si crystallizes in the cubic Im-3m space group. The structure is three-dimensional. Ce is bonded to twelve Rh atoms to form CeRh12 cuboctahedra that share corners with twelve equivalent CeRh12 cuboctahedra, faces with six equivalent CeRh12 cuboctahedra, and faces with two equivalent SiRh6 octahedra. There are six shorter (2.94 Å) and six longer (2.95 Å) Ce–Rh bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded in a distorted square co-planar geometry to four equivalent Ce atoms. In the second Rh site, Rh is bonded in a 5-coordinate geometry to four equivalent Ce and one Si atom. The Rh–Si bond length is 2.32 Å. Si is bonded to six equivalent Rh atoms to form SiRh6 octahedra that share faces with eight equivalent CeRh12 cuboctahedra.},
doi = {10.17188/1729406},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}