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Title: Materials Data on Ag3Pb by Materials Project

Abstract

Ag3Pb crystallizes in the hexagonal P-6m2 space group. The structure is three-dimensional. there are two inequivalent Ag sites. In the first Ag site, Ag is bonded to twelve Ag atoms to form AgAg12 cuboctahedra that share corners with six equivalent AgAg12 cuboctahedra, corners with twelve equivalent PbAg6Pb6 cuboctahedra, edges with eighteen AgAg12 cuboctahedra, faces with two equivalent PbAg6Pb6 cuboctahedra, and faces with eighteen AgAg12 cuboctahedra. There are six shorter (2.89 Å) and six longer (3.25 Å) Ag–Ag bond lengths. In the second Ag site, Ag is bonded to nine Ag and three equivalent Pb atoms to form distorted AgAg9Pb3 cuboctahedra that share corners with eighteen equivalent AgAg9Pb3 cuboctahedra, edges with six equivalent PbAg6Pb6 cuboctahedra, edges with twelve AgAg12 cuboctahedra, faces with six equivalent PbAg6Pb6 cuboctahedra, and faces with fourteen AgAg12 cuboctahedra. All Ag–Ag bond lengths are 3.25 Å. All Ag–Pb bond lengths are 3.16 Å. Pb is bonded to six equivalent Ag and six equivalent Pb atoms to form distorted PbAg6Pb6 cuboctahedra that share corners with six equivalent PbAg6Pb6 cuboctahedra, corners with twelve equivalent AgAg12 cuboctahedra, edges with six equivalent PbAg6Pb6 cuboctahedra, edges with twelve equivalent AgAg9Pb3 cuboctahedra, faces with six equivalent PbAg6Pb6 cuboctahedra, and faces with fourteen AgAg12 cuboctahedra.more » All Pb–Pb bond lengths are 3.25 Å.« less

Publication Date:
Other Number(s):
mp-1229123
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ag3Pb; Ag-Pb
OSTI Identifier:
1729056
DOI:
https://doi.org/10.17188/1729056

Citation Formats

The Materials Project. Materials Data on Ag3Pb by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1729056.
The Materials Project. Materials Data on Ag3Pb by Materials Project. United States. doi:https://doi.org/10.17188/1729056
The Materials Project. 2019. "Materials Data on Ag3Pb by Materials Project". United States. doi:https://doi.org/10.17188/1729056. https://www.osti.gov/servlets/purl/1729056. Pub date:Sun Jan 13 00:00:00 EST 2019
@article{osti_1729056,
title = {Materials Data on Ag3Pb by Materials Project},
author = {The Materials Project},
abstractNote = {Ag3Pb crystallizes in the hexagonal P-6m2 space group. The structure is three-dimensional. there are two inequivalent Ag sites. In the first Ag site, Ag is bonded to twelve Ag atoms to form AgAg12 cuboctahedra that share corners with six equivalent AgAg12 cuboctahedra, corners with twelve equivalent PbAg6Pb6 cuboctahedra, edges with eighteen AgAg12 cuboctahedra, faces with two equivalent PbAg6Pb6 cuboctahedra, and faces with eighteen AgAg12 cuboctahedra. There are six shorter (2.89 Å) and six longer (3.25 Å) Ag–Ag bond lengths. In the second Ag site, Ag is bonded to nine Ag and three equivalent Pb atoms to form distorted AgAg9Pb3 cuboctahedra that share corners with eighteen equivalent AgAg9Pb3 cuboctahedra, edges with six equivalent PbAg6Pb6 cuboctahedra, edges with twelve AgAg12 cuboctahedra, faces with six equivalent PbAg6Pb6 cuboctahedra, and faces with fourteen AgAg12 cuboctahedra. All Ag–Ag bond lengths are 3.25 Å. All Ag–Pb bond lengths are 3.16 Å. Pb is bonded to six equivalent Ag and six equivalent Pb atoms to form distorted PbAg6Pb6 cuboctahedra that share corners with six equivalent PbAg6Pb6 cuboctahedra, corners with twelve equivalent AgAg12 cuboctahedra, edges with six equivalent PbAg6Pb6 cuboctahedra, edges with twelve equivalent AgAg9Pb3 cuboctahedra, faces with six equivalent PbAg6Pb6 cuboctahedra, and faces with fourteen AgAg12 cuboctahedra. All Pb–Pb bond lengths are 3.25 Å.},
doi = {10.17188/1729056},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}