U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Tb2Co17 by Materials Project
Abstract
Tb2Co17 crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. there are two inequivalent Tb sites. In the first Tb site, Tb is bonded in a 12-coordinate geometry to eighteen Co atoms. There are a spread of Tb–Co bond distances ranging from 2.95–3.25 Å. In the second Tb site, Tb is bonded in a 2-coordinate geometry to twenty Co atoms. There are a spread of Tb–Co bond distances ranging from 2.90–3.14 Å. There are four inequivalent Co sites. In the first Co site, Co is bonded in a 2-coordinate geometry to one Tb and thirteen Co atoms. There are a spread of Co–Co bond distances ranging from 2.32–2.66 Å. In the second Co site, Co is bonded to two equivalent Tb and ten Co atoms to form CoTb2Co10 cuboctahedra that share corners with fourteen CoTb2Co10 cuboctahedra, edges with six equivalent CoTb3Co9 cuboctahedra, and faces with ten CoTb2Co10 cuboctahedra. There are four shorter (2.39 Å) and four longer (2.40 Å) Co–Co bond lengths. In the third Co site, Co is bonded in a 12-coordinate geometry to two Tb and ten Co atoms. There are a spread of Co–Co bond distances ranging from 2.33–2.56 Å. In the fourth Co site,more »
- Authors:
- Publication Date:
- Other Number(s):
- mp-1199370
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Tb2Co17; Co-Tb
- OSTI Identifier:
- 1726920
- DOI:
- https://doi.org/10.17188/1726920
Citation Formats
The Materials Project. Materials Data on Tb2Co17 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1726920.
The Materials Project. Materials Data on Tb2Co17 by Materials Project. United States. doi:https://doi.org/10.17188/1726920
The Materials Project. 2020.
"Materials Data on Tb2Co17 by Materials Project". United States. doi:https://doi.org/10.17188/1726920. https://www.osti.gov/servlets/purl/1726920. Pub date:Fri Jun 05 00:00:00 EDT 2020
@article{osti_1726920,
title = {Materials Data on Tb2Co17 by Materials Project},
author = {The Materials Project},
abstractNote = {Tb2Co17 crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. there are two inequivalent Tb sites. In the first Tb site, Tb is bonded in a 12-coordinate geometry to eighteen Co atoms. There are a spread of Tb–Co bond distances ranging from 2.95–3.25 Å. In the second Tb site, Tb is bonded in a 2-coordinate geometry to twenty Co atoms. There are a spread of Tb–Co bond distances ranging from 2.90–3.14 Å. There are four inequivalent Co sites. In the first Co site, Co is bonded in a 2-coordinate geometry to one Tb and thirteen Co atoms. There are a spread of Co–Co bond distances ranging from 2.32–2.66 Å. In the second Co site, Co is bonded to two equivalent Tb and ten Co atoms to form CoTb2Co10 cuboctahedra that share corners with fourteen CoTb2Co10 cuboctahedra, edges with six equivalent CoTb3Co9 cuboctahedra, and faces with ten CoTb2Co10 cuboctahedra. There are four shorter (2.39 Å) and four longer (2.40 Å) Co–Co bond lengths. In the third Co site, Co is bonded in a 12-coordinate geometry to two Tb and ten Co atoms. There are a spread of Co–Co bond distances ranging from 2.33–2.56 Å. In the fourth Co site, Co is bonded to three Tb and nine Co atoms to form a mixture of distorted corner, edge, and face-sharing CoTb3Co9 cuboctahedra. Both Co–Co bond lengths are 2.42 Å.},
doi = {10.17188/1726920},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {6}
}