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Title: Materials Data on Na2HgMoF6 by Materials Project

Abstract

(Na)2MoHgF6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of eight sodium molecules and one MoHgF6 framework. In the MoHgF6 framework, Mo2+ is bonded to six equivalent F1- atoms to form MoF6 octahedra that share corners with six equivalent HgF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Mo–F bond lengths are 1.98 Å. Hg2+ is bonded to six equivalent F1- atoms to form HgF6 octahedra that share corners with six equivalent MoF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Hg–F bond lengths are 2.83 Å. F1- is bonded in a distorted linear geometry to one Mo2+ and one Hg2+ atom.

Authors:
Publication Date:
Other Number(s):
mp-1111063
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Na2HgMoF6; F-Hg-Mo-Na
OSTI Identifier:
1722248
DOI:
https://doi.org/10.17188/1722248

Citation Formats

The Materials Project. Materials Data on Na2HgMoF6 by Materials Project. United States: N. p., 2018. Web. doi:10.17188/1722248.
The Materials Project. Materials Data on Na2HgMoF6 by Materials Project. United States. doi:https://doi.org/10.17188/1722248
The Materials Project. 2018. "Materials Data on Na2HgMoF6 by Materials Project". United States. doi:https://doi.org/10.17188/1722248. https://www.osti.gov/servlets/purl/1722248. Pub date:Wed Aug 15 00:00:00 EDT 2018
@article{osti_1722248,
title = {Materials Data on Na2HgMoF6 by Materials Project},
author = {The Materials Project},
abstractNote = {(Na)2MoHgF6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of eight sodium molecules and one MoHgF6 framework. In the MoHgF6 framework, Mo2+ is bonded to six equivalent F1- atoms to form MoF6 octahedra that share corners with six equivalent HgF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Mo–F bond lengths are 1.98 Å. Hg2+ is bonded to six equivalent F1- atoms to form HgF6 octahedra that share corners with six equivalent MoF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Hg–F bond lengths are 2.83 Å. F1- is bonded in a distorted linear geometry to one Mo2+ and one Hg2+ atom.},
doi = {10.17188/1722248},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {8}
}