U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on SbNF4 by Materials Project
Abstract
N2SbF3SbF5 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ammonia molecules, four antimony trifluoride molecules, and four SbF5 clusters. In each SbF5 cluster, Sb3+ is bonded in a trigonal bipyramidal geometry to five F1- atoms. There is four shorter (1.89 Å) and one longer (1.90 Å) Sb–F bond length. There are five inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom.
- Publication Date:
- Other Number(s):
- mp-1202415
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; F-N-Sb; SbNF4; crystal structure
- OSTI Identifier:
- 1722100
- DOI:
- https://doi.org/10.17188/1722100
Citation Formats
Materials Data on SbNF4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1722100.
Materials Data on SbNF4 by Materials Project. United States. doi:https://doi.org/10.17188/1722100
2020.
"Materials Data on SbNF4 by Materials Project". United States. doi:https://doi.org/10.17188/1722100. https://www.osti.gov/servlets/purl/1722100. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1722100,
title = {Materials Data on SbNF4 by Materials Project},
abstractNote = {N2SbF3SbF5 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ammonia molecules, four antimony trifluoride molecules, and four SbF5 clusters. In each SbF5 cluster, Sb3+ is bonded in a trigonal bipyramidal geometry to five F1- atoms. There is four shorter (1.89 Å) and one longer (1.90 Å) Sb–F bond length. There are five inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom.},
doi = {10.17188/1722100},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}