Materials Data on Ce(SnRh)2 by Materials Project

doi:10.17188/1721852

Title: Materials Data on Ce(SnRh)2 by Materials Project

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Abstract

Ce(RhSn)2 crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. Ce is bonded in a 12-coordinate geometry to eight Rh and eight Sn atoms. There are four shorter (3.45 Å) and four longer (3.48 Å) Ce–Rh bond lengths. There are four shorter (3.44 Å) and four longer (3.53 Å) Ce–Sn bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded in a 4-coordinate geometry to four equivalent Ce and four equivalent Sn atoms. All Rh–Sn bond lengths are 2.64 Å. In the second Rh site, Rh is bonded in a 9-coordinate geometry to four equivalent Ce and five Sn atoms. There are one shorter (2.57 Å) and four longer (2.67 Å) Rh–Sn bond lengths. There are two inequivalent Sn sites. In the first Sn site, Sn is bonded to four equivalent Ce and four equivalent Rh atoms to form a mixture of distorted face and edge-sharing SnCe4Rh4 tetrahedra. In the second Sn site, Sn is bonded in a 9-coordinate geometry to four equivalent Ce and five Rh atoms.

Publication Date:: 2020-05-01

Other Number(s):: mp-1079827

DOE Contract Number:: AC02-05CH11231;

Research Org.:: LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Collaborations:: The Materials Project; MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE; Ce(SnRh)2; Ce-Rh-Sn; crystal structure

OSTI Identifier:: 1721852

DOI:: https://doi.org/10.17188/1721852

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                    Materials Data on Ce(SnRh)2 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1721852.

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                    Materials Data on Ce(SnRh)2 by Materials Project.  United States.  doi:https://doi.org/10.17188/1721852

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                    2020.  
"Materials Data on Ce(SnRh)2 by Materials Project".  United States.  doi:https://doi.org/10.17188/1721852.  https://www.osti.gov/servlets/purl/1721852. Pub date:Fri May 01 20:00:00 EDT 2020

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@article{osti_1721852,

  title        = {Materials Data on Ce(SnRh)2 by Materials Project},

  
  abstractNote = {Ce(RhSn)2 crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. Ce is bonded in a 12-coordinate geometry to eight Rh and eight Sn atoms. There are four shorter (3.45 Å) and four longer (3.48 Å) Ce–Rh bond lengths. There are four shorter (3.44 Å) and four longer (3.53 Å) Ce–Sn bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded in a 4-coordinate geometry to four equivalent Ce and four equivalent Sn atoms. All Rh–Sn bond lengths are 2.64 Å. In the second Rh site, Rh is bonded in a 9-coordinate geometry to four equivalent Ce and five Sn atoms. There are one shorter (2.57 Å) and four longer (2.67 Å) Rh–Sn bond lengths. There are two inequivalent Sn sites. In the first Sn site, Sn is bonded to four equivalent Ce and four equivalent Rh atoms to form a mixture of distorted face and edge-sharing SnCe4Rh4 tetrahedra. In the second Sn site, Sn is bonded in a 9-coordinate geometry to four equivalent Ce and five Rh atoms.},

  doi          = {10.17188/1721852},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {5}

}

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DOI: https://doi.org/10.17188/1721852

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