U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Na2Sb3O8 by Materials Project
Abstract
Na2Sb3O8 crystallizes in the cubic P4_332 space group. The structure is three-dimensional. Na is bonded to four O atoms to form NaO4 tetrahedra that share corners with nine equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 54–60°. There are three shorter (2.32 Å) and one longer (2.33 Å) Na–O bond lengths. Sb is bonded to six O atoms to form SbO6 octahedra that share corners with six equivalent NaO4 tetrahedra and edges with four equivalent SbO6 octahedra. There are a spread of Sb–O bond distances ranging from 2.01–2.17 Å. There are two inequivalent O sites. In the first O site, O is bonded in a trigonal planar geometry to one Na and two equivalent Sb atoms. In the second O site, O is bonded to one Na and three equivalent Sb atoms to form distorted corner-sharing ONaSb3 tetrahedra.
- Publication Date:
- Other Number(s):
- mp-1176363
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Na-O-Sb; Na2Sb3O8; crystal structure
- OSTI Identifier:
- 1719668
- DOI:
- https://doi.org/10.17188/1719668
Citation Formats
Materials Data on Na2Sb3O8 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1719668.
Materials Data on Na2Sb3O8 by Materials Project. United States. doi:https://doi.org/10.17188/1719668
2020.
"Materials Data on Na2Sb3O8 by Materials Project". United States. doi:https://doi.org/10.17188/1719668. https://www.osti.gov/servlets/purl/1719668. Pub date:Wed Apr 29 04:00:00 UTC 2020
@article{osti_1719668,
title = {Materials Data on Na2Sb3O8 by Materials Project},
abstractNote = {Na2Sb3O8 crystallizes in the cubic P4_332 space group. The structure is three-dimensional. Na is bonded to four O atoms to form NaO4 tetrahedra that share corners with nine equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 54–60°. There are three shorter (2.32 Å) and one longer (2.33 Å) Na–O bond lengths. Sb is bonded to six O atoms to form SbO6 octahedra that share corners with six equivalent NaO4 tetrahedra and edges with four equivalent SbO6 octahedra. There are a spread of Sb–O bond distances ranging from 2.01–2.17 Å. There are two inequivalent O sites. In the first O site, O is bonded in a trigonal planar geometry to one Na and two equivalent Sb atoms. In the second O site, O is bonded to one Na and three equivalent Sb atoms to form distorted corner-sharing ONaSb3 tetrahedra.},
doi = {10.17188/1719668},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}