Materials Data on Yb2EuS4 by Materials Project

doi:10.17188/1718760

Title: Materials Data on Yb2EuS4 by Materials Project

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Abstract

EuYb2S4 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. there are two inequivalent Yb3+ sites. In the first Yb3+ site, Yb3+ is bonded to six S2- atoms to form a mixture of distorted edge and corner-sharing YbS6 octahedra. The corner-sharing octahedra tilt angles range from 53–73°. There are a spread of Yb–S bond distances ranging from 2.72–3.07 Å. In the second Yb3+ site, Yb3+ is bonded to six S2- atoms to form a mixture of distorted edge and corner-sharing YbS6 octahedra. The corner-sharing octahedra tilt angles range from 53–73°. There are a spread of Yb–S bond distances ranging from 2.65–3.33 Å. Eu2+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Eu–S bond distances ranging from 2.95–3.20 Å. There are four inequivalent S2- sites. In the first S2- site, S2- is bonded to three Yb3+ and two equivalent Eu2+ atoms to form distorted edge-sharing SYb3Eu2 square pyramids. In the second S2- site, S2- is bonded in a 6-coordinate geometry to three equivalent Yb3+, two equivalent Eu2+, and one S2- atom. The S–S bond length is 2.20 Å. In the third S2- site, S2- is bonded to three Yb3+ and two equivalentmore »« less

Authors:: The Materials Project

Publication Date:: 2020-05-02

Other Number(s):: mp-1194516

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; Yb2EuS4; Eu-S-Yb

OSTI Identifier:: 1718760

DOI:: https://doi.org/10.17188/1718760

Citation Formats


                    The Materials Project. Materials Data on Yb2EuS4 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1718760.

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                    The Materials Project. Materials Data on Yb2EuS4 by Materials Project.  United States.  doi:https://doi.org/10.17188/1718760

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                    The Materials Project. 2020.  
"Materials Data on Yb2EuS4 by Materials Project".  United States.  doi:https://doi.org/10.17188/1718760.  https://www.osti.gov/servlets/purl/1718760. Pub date:Sat May 02 00:00:00 EDT 2020

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@article{osti_1718760,

  title        = {Materials Data on Yb2EuS4 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {EuYb2S4 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. there are two inequivalent Yb3+ sites. In the first Yb3+ site, Yb3+ is bonded to six S2- atoms to form a mixture of distorted edge and corner-sharing YbS6 octahedra. The corner-sharing octahedra tilt angles range from 53–73°. There are a spread of Yb–S bond distances ranging from 2.72–3.07 Å. In the second Yb3+ site, Yb3+ is bonded to six S2- atoms to form a mixture of distorted edge and corner-sharing YbS6 octahedra. The corner-sharing octahedra tilt angles range from 53–73°. There are a spread of Yb–S bond distances ranging from 2.65–3.33 Å. Eu2+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Eu–S bond distances ranging from 2.95–3.20 Å. There are four inequivalent S2- sites. In the first S2- site, S2- is bonded to three Yb3+ and two equivalent Eu2+ atoms to form distorted edge-sharing SYb3Eu2 square pyramids. In the second S2- site, S2- is bonded in a 6-coordinate geometry to three equivalent Yb3+, two equivalent Eu2+, and one S2- atom. The S–S bond length is 2.20 Å. In the third S2- site, S2- is bonded to three Yb3+ and two equivalent Eu2+ atoms to form a mixture of distorted edge and corner-sharing SYb3Eu2 trigonal bipyramids. In the fourth S2- site, S2- is bonded in a 6-coordinate geometry to three equivalent Yb3+, two equivalent Eu2+, and one S2- atom.},

  doi          = {10.17188/1718760},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {5}

}

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DOI: https://doi.org/10.17188/1718760

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