U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Cd(CoO2)2 by Materials Project
Abstract
Cd(CoO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Co3+ is bonded to six equivalent O2- atoms to form distorted CoO6 octahedra that share corners with six equivalent CdO4 tetrahedra and edges with six equivalent CoO6 octahedra. There are four shorter (1.93 Å) and two longer (2.23 Å) Co–O bond lengths. Cd2+ is bonded to four equivalent O2- atoms to form CdO4 tetrahedra that share corners with twelve equivalent CoO6 octahedra. The corner-sharing octahedra tilt angles range from 54–65°. All Cd–O bond lengths are 2.18 Å. O2- is bonded to three equivalent Co3+ and one Cd2+ atom to form a mixture of distorted edge and corner-sharing OCdCo3 tetrahedra.
- Publication Date:
- Other Number(s):
- mp-1178498
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Cd(CoO2)2; Cd-Co-O; crystal structure
- OSTI Identifier:
- 1718646
- DOI:
- https://doi.org/10.17188/1718646
Citation Formats
Materials Data on Cd(CoO2)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1718646.
Materials Data on Cd(CoO2)2 by Materials Project. United States. doi:https://doi.org/10.17188/1718646
2020.
"Materials Data on Cd(CoO2)2 by Materials Project". United States. doi:https://doi.org/10.17188/1718646. https://www.osti.gov/servlets/purl/1718646. Pub date:Mon May 04 00:00:00 EDT 2020
@article{osti_1718646,
title = {Materials Data on Cd(CoO2)2 by Materials Project},
abstractNote = {Cd(CoO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Co3+ is bonded to six equivalent O2- atoms to form distorted CoO6 octahedra that share corners with six equivalent CdO4 tetrahedra and edges with six equivalent CoO6 octahedra. There are four shorter (1.93 Å) and two longer (2.23 Å) Co–O bond lengths. Cd2+ is bonded to four equivalent O2- atoms to form CdO4 tetrahedra that share corners with twelve equivalent CoO6 octahedra. The corner-sharing octahedra tilt angles range from 54–65°. All Cd–O bond lengths are 2.18 Å. O2- is bonded to three equivalent Co3+ and one Cd2+ atom to form a mixture of distorted edge and corner-sharing OCdCo3 tetrahedra.},
doi = {10.17188/1718646},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}
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