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Title: Materials Data on Cd(CoO2)2 by Materials Project

Abstract

Cd(CoO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Co3+ is bonded to six equivalent O2- atoms to form distorted CoO6 octahedra that share corners with six equivalent CdO4 tetrahedra and edges with six equivalent CoO6 octahedra. There are four shorter (1.93 Å) and two longer (2.23 Å) Co–O bond lengths. Cd2+ is bonded to four equivalent O2- atoms to form CdO4 tetrahedra that share corners with twelve equivalent CoO6 octahedra. The corner-sharing octahedra tilt angles range from 54–65°. All Cd–O bond lengths are 2.18 Å. O2- is bonded to three equivalent Co3+ and one Cd2+ atom to form a mixture of distorted edge and corner-sharing OCdCo3 tetrahedra.

Authors:
Publication Date:
Other Number(s):
mp-1178498
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Cd(CoO2)2; Cd-Co-O
OSTI Identifier:
1718646
DOI:
https://doi.org/10.17188/1718646

Citation Formats

The Materials Project. Materials Data on Cd(CoO2)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1718646.
The Materials Project. Materials Data on Cd(CoO2)2 by Materials Project. United States. doi:https://doi.org/10.17188/1718646
The Materials Project. 2020. "Materials Data on Cd(CoO2)2 by Materials Project". United States. doi:https://doi.org/10.17188/1718646. https://www.osti.gov/servlets/purl/1718646. Pub date:Mon May 04 00:00:00 EDT 2020
@article{osti_1718646,
title = {Materials Data on Cd(CoO2)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Cd(CoO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Co3+ is bonded to six equivalent O2- atoms to form distorted CoO6 octahedra that share corners with six equivalent CdO4 tetrahedra and edges with six equivalent CoO6 octahedra. There are four shorter (1.93 Å) and two longer (2.23 Å) Co–O bond lengths. Cd2+ is bonded to four equivalent O2- atoms to form CdO4 tetrahedra that share corners with twelve equivalent CoO6 octahedra. The corner-sharing octahedra tilt angles range from 54–65°. All Cd–O bond lengths are 2.18 Å. O2- is bonded to three equivalent Co3+ and one Cd2+ atom to form a mixture of distorted edge and corner-sharing OCdCo3 tetrahedra.},
doi = {10.17188/1718646},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}