skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on Li(RhO2)3 by Materials Project

Abstract

Li(RhO2)2RhO2 crystallizes in the orthorhombic Cmmm space group. The structure is two-dimensional and consists of two rhodium molecules; four water molecules; and one Li(RhO2)2 sheet oriented in the (0, 0, 1) direction. In the Li(RhO2)2 sheet, there are two inequivalent Li1+ sites. In the first Li1+ site, Li1+ is bonded in a square co-planar geometry to four equivalent O2- atoms. All Li–O bond lengths are 1.96 Å. In the second Li1+ site, Li1+ is bonded in a rectangular see-saw-like geometry to four equivalent O2- atoms. All Li–O bond lengths are 1.96 Å. Rh+3.67+ is bonded in a linear geometry to two O2- atoms. Both Rh–O bond lengths are 1.92 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 2-coordinate geometry to one Li1+, one Rh+3.67+, and one O2- atom. The O–O bond length is 1.49 Å. In the second O2- site, O2- is bonded in a 2-coordinate geometry to one Li1+, one Rh+3.67+, and one O2- atom. The O–O bond length is 1.49 Å.

Publication Date:
Other Number(s):
mp-1207037
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Li(RhO2)3; Li-O-Rh
OSTI Identifier:
1716917
DOI:
https://doi.org/10.17188/1716917

Citation Formats

The Materials Project. Materials Data on Li(RhO2)3 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1716917.
The Materials Project. Materials Data on Li(RhO2)3 by Materials Project. United States. doi:https://doi.org/10.17188/1716917
The Materials Project. 2019. "Materials Data on Li(RhO2)3 by Materials Project". United States. doi:https://doi.org/10.17188/1716917. https://www.osti.gov/servlets/purl/1716917. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1716917,
title = {Materials Data on Li(RhO2)3 by Materials Project},
author = {The Materials Project},
abstractNote = {Li(RhO2)2RhO2 crystallizes in the orthorhombic Cmmm space group. The structure is two-dimensional and consists of two rhodium molecules; four water molecules; and one Li(RhO2)2 sheet oriented in the (0, 0, 1) direction. In the Li(RhO2)2 sheet, there are two inequivalent Li1+ sites. In the first Li1+ site, Li1+ is bonded in a square co-planar geometry to four equivalent O2- atoms. All Li–O bond lengths are 1.96 Å. In the second Li1+ site, Li1+ is bonded in a rectangular see-saw-like geometry to four equivalent O2- atoms. All Li–O bond lengths are 1.96 Å. Rh+3.67+ is bonded in a linear geometry to two O2- atoms. Both Rh–O bond lengths are 1.92 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 2-coordinate geometry to one Li1+, one Rh+3.67+, and one O2- atom. The O–O bond length is 1.49 Å. In the second O2- site, O2- is bonded in a 2-coordinate geometry to one Li1+, one Rh+3.67+, and one O2- atom. The O–O bond length is 1.49 Å.},
doi = {10.17188/1716917},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}