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Title: Materials Data on UV5P3 by Materials Project

Abstract

UV5P3 crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. U is bonded in a 12-coordinate geometry to six P atoms. There are a spread of U–P bond distances ranging from 2.82–2.84 Å. There are five inequivalent V sites. In the first V site, V is bonded to four P atoms to form a mixture of distorted corner and edge-sharing VP4 tetrahedra. There are a spread of V–P bond distances ranging from 2.38–2.50 Å. In the second V site, V is bonded to four P atoms to form a mixture of distorted corner and edge-sharing VP4 tetrahedra. There are a spread of V–P bond distances ranging from 2.38–2.48 Å. In the third V site, V is bonded in a 4-coordinate geometry to four P atoms. There are a spread of V–P bond distances ranging from 2.40–2.47 Å. In the fourth V site, V is bonded in a 4-coordinate geometry to four P atoms. There are a spread of V–P bond distances ranging from 2.44–2.55 Å. In the fifth V site, V is bonded in a 5-coordinate geometry to five P atoms. There are four shorter (2.51 Å) and one longer (2.61 Å) V–P bond lengths. There are threemore » inequivalent P sites. In the first P site, P is bonded in a 9-coordinate geometry to two equivalent U and seven V atoms. In the second P site, P is bonded in a 9-coordinate geometry to two equivalent U and seven V atoms. In the third P site, P is bonded in a 9-coordinate geometry to two equivalent U and seven V atoms.« less

Publication Date:
Other Number(s):
mp-1207879
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; UV5P3; P-U-V
OSTI Identifier:
1715080
DOI:
https://doi.org/10.17188/1715080

Citation Formats

The Materials Project. Materials Data on UV5P3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1715080.
The Materials Project. Materials Data on UV5P3 by Materials Project. United States. doi:https://doi.org/10.17188/1715080
The Materials Project. 2020. "Materials Data on UV5P3 by Materials Project". United States. doi:https://doi.org/10.17188/1715080. https://www.osti.gov/servlets/purl/1715080. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1715080,
title = {Materials Data on UV5P3 by Materials Project},
author = {The Materials Project},
abstractNote = {UV5P3 crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. U is bonded in a 12-coordinate geometry to six P atoms. There are a spread of U–P bond distances ranging from 2.82–2.84 Å. There are five inequivalent V sites. In the first V site, V is bonded to four P atoms to form a mixture of distorted corner and edge-sharing VP4 tetrahedra. There are a spread of V–P bond distances ranging from 2.38–2.50 Å. In the second V site, V is bonded to four P atoms to form a mixture of distorted corner and edge-sharing VP4 tetrahedra. There are a spread of V–P bond distances ranging from 2.38–2.48 Å. In the third V site, V is bonded in a 4-coordinate geometry to four P atoms. There are a spread of V–P bond distances ranging from 2.40–2.47 Å. In the fourth V site, V is bonded in a 4-coordinate geometry to four P atoms. There are a spread of V–P bond distances ranging from 2.44–2.55 Å. In the fifth V site, V is bonded in a 5-coordinate geometry to five P atoms. There are four shorter (2.51 Å) and one longer (2.61 Å) V–P bond lengths. There are three inequivalent P sites. In the first P site, P is bonded in a 9-coordinate geometry to two equivalent U and seven V atoms. In the second P site, P is bonded in a 9-coordinate geometry to two equivalent U and seven V atoms. In the third P site, P is bonded in a 9-coordinate geometry to two equivalent U and seven V atoms.},
doi = {10.17188/1715080},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}