U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Co(IO4)2 by Materials Project
Abstract
Co(O4I)2 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one Co(O4I)2 sheet oriented in the (1, 1, 0) direction. there are two inequivalent Co sites. In the first Co site, Co is bonded in an octahedral geometry to six O atoms. There are a spread of Co–O bond distances ranging from 1.74–1.94 Å. In the second Co site, Co is bonded in an octahedral geometry to six O atoms. There are a spread of Co–O bond distances ranging from 1.76–1.93 Å. There are eight inequivalent O sites. In the first O site, O is bonded in a distorted bent 150 degrees geometry to one Co and one I atom. The O–I bond length is 1.87 Å. In the second O site, O is bonded in a distorted bent 120 degrees geometry to one Co and one I atom. The O–I bond length is 1.91 Å. In the third O site, O is bonded in a single-bond geometry to one I atom. The O–I bond length is 1.81 Å. In the fourth O site, O is bonded in a single-bond geometry to one Co atom. In the fifth O site, O is bonded in amore »
- Publication Date:
- Other Number(s):
- mp-1191448
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Co(IO4)2; Co-I-O; crystal structure
- OSTI Identifier:
- 1711157
- DOI:
- https://doi.org/10.17188/1711157
Citation Formats
Materials Data on Co(IO4)2 by Materials Project. United States: N. p., 2019.
Web. doi:10.17188/1711157.
Materials Data on Co(IO4)2 by Materials Project. United States. doi:https://doi.org/10.17188/1711157
2019.
"Materials Data on Co(IO4)2 by Materials Project". United States. doi:https://doi.org/10.17188/1711157. https://www.osti.gov/servlets/purl/1711157. Pub date:Fri Jan 11 04:00:00 UTC 2019
@article{osti_1711157,
title = {Materials Data on Co(IO4)2 by Materials Project},
abstractNote = {Co(O4I)2 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one Co(O4I)2 sheet oriented in the (1, 1, 0) direction. there are two inequivalent Co sites. In the first Co site, Co is bonded in an octahedral geometry to six O atoms. There are a spread of Co–O bond distances ranging from 1.74–1.94 Å. In the second Co site, Co is bonded in an octahedral geometry to six O atoms. There are a spread of Co–O bond distances ranging from 1.76–1.93 Å. There are eight inequivalent O sites. In the first O site, O is bonded in a distorted bent 150 degrees geometry to one Co and one I atom. The O–I bond length is 1.87 Å. In the second O site, O is bonded in a distorted bent 120 degrees geometry to one Co and one I atom. The O–I bond length is 1.91 Å. In the third O site, O is bonded in a single-bond geometry to one I atom. The O–I bond length is 1.81 Å. In the fourth O site, O is bonded in a single-bond geometry to one Co atom. In the fifth O site, O is bonded in a water-like geometry to one Co and one I atom. The O–I bond length is 1.91 Å. In the sixth O site, O is bonded in a bent 120 degrees geometry to one Co and one I atom. The O–I bond length is 1.87 Å. In the seventh O site, O is bonded in a distorted bent 150 degrees geometry to two I atoms. There are one shorter (1.81 Å) and one longer (2.50 Å) O–I bond lengths. In the eighth O site, O is bonded in a single-bond geometry to one Co atom. There are two inequivalent I sites. In the first I site, I is bonded in a 5-coordinate geometry to four O atoms. In the second I site, I is bonded in a 6-coordinate geometry to three O atoms.},
doi = {10.17188/1711157},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}