Materials Data on La2(B2Rh3)3 by Materials Project
Abstract
La2(Rh3B2)3 crystallizes in the hexagonal P6/mmm space group. The structure is three-dimensional. La is bonded in a 6-coordinate geometry to six equivalent Rh atoms. All La–Rh bond lengths are 3.04 Å. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded in a 6-coordinate geometry to two equivalent La and four B atoms. There are two shorter (2.16 Å) and two longer (2.20 Å) Rh–B bond lengths. In the second Rh site, Rh is bonded in a distorted square co-planar geometry to four equivalent B atoms. All Rh–B bond lengths are 2.18 Å. There are two inequivalent B sites. In the first B site, B is bonded to six equivalent Rh atoms to form distorted edge-sharing BRh6 pentagonal pyramids. In the second B site, B is bonded in a 6-coordinate geometry to six Rh atoms.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1223329
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; La2(B2Rh3)3; B-La-Rh
- OSTI Identifier:
- 1711002
- DOI:
- https://doi.org/10.17188/1711002
Citation Formats
The Materials Project. Materials Data on La2(B2Rh3)3 by Materials Project. United States: N. p., 2019.
Web. doi:10.17188/1711002.
The Materials Project. Materials Data on La2(B2Rh3)3 by Materials Project. United States. doi:https://doi.org/10.17188/1711002
The Materials Project. 2019.
"Materials Data on La2(B2Rh3)3 by Materials Project". United States. doi:https://doi.org/10.17188/1711002. https://www.osti.gov/servlets/purl/1711002. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1711002,
title = {Materials Data on La2(B2Rh3)3 by Materials Project},
author = {The Materials Project},
abstractNote = {La2(Rh3B2)3 crystallizes in the hexagonal P6/mmm space group. The structure is three-dimensional. La is bonded in a 6-coordinate geometry to six equivalent Rh atoms. All La–Rh bond lengths are 3.04 Å. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded in a 6-coordinate geometry to two equivalent La and four B atoms. There are two shorter (2.16 Å) and two longer (2.20 Å) Rh–B bond lengths. In the second Rh site, Rh is bonded in a distorted square co-planar geometry to four equivalent B atoms. All Rh–B bond lengths are 2.18 Å. There are two inequivalent B sites. In the first B site, B is bonded to six equivalent Rh atoms to form distorted edge-sharing BRh6 pentagonal pyramids. In the second B site, B is bonded in a 6-coordinate geometry to six Rh atoms.},
doi = {10.17188/1711002},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}