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Title: Materials Data on AgH15N8 by Materials Project

Abstract

(Ag(NH3)4)2(N2)3(NH3)2 crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four ammonia molecules, four triazane molecules, and four Ag(NH3)4 clusters. In each Ag(NH3)4 cluster, Ag1+ is bonded in a tetrahedral geometry to four N2- atoms. There are a spread of Ag–N bond distances ranging from 2.30–2.38 Å. There are four inequivalent N2- sites. In the first N2- site, N2- is bonded in a trigonal non-coplanar geometry to one Ag1+ and three H1+ atoms. All N–H bond lengths are 1.02 Å. In the second N2- site, N2- is bonded in a trigonal non-coplanar geometry to one Ag1+ and three H1+ atoms. All N–H bond lengths are 1.02 Å. In the third N2- site, N2- is bonded in a distorted trigonal non-coplanar geometry to one Ag1+ and three H1+ atoms. There is two shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. In the fourth N2- site, N2- is bonded in a trigonal non-coplanar geometry to one Ag1+ and three H1+ atoms. All N–H bond lengths are 1.02 Å. There are twelve inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the second H1+more » site, H1+ is bonded in a single-bond geometry to one N2- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the seventh H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the eighth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the ninth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the tenth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the eleventh H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the twelfth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom.« less

Publication Date:
Other Number(s):
mp-1194820
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; AgH15N8; Ag-H-N
OSTI Identifier:
1710607
DOI:
https://doi.org/10.17188/1710607

Citation Formats

The Materials Project. Materials Data on AgH15N8 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1710607.
The Materials Project. Materials Data on AgH15N8 by Materials Project. United States. doi:https://doi.org/10.17188/1710607
The Materials Project. 2019. "Materials Data on AgH15N8 by Materials Project". United States. doi:https://doi.org/10.17188/1710607. https://www.osti.gov/servlets/purl/1710607. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1710607,
title = {Materials Data on AgH15N8 by Materials Project},
author = {The Materials Project},
abstractNote = {(Ag(NH3)4)2(N2)3(NH3)2 crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four ammonia molecules, four triazane molecules, and four Ag(NH3)4 clusters. In each Ag(NH3)4 cluster, Ag1+ is bonded in a tetrahedral geometry to four N2- atoms. There are a spread of Ag–N bond distances ranging from 2.30–2.38 Å. There are four inequivalent N2- sites. In the first N2- site, N2- is bonded in a trigonal non-coplanar geometry to one Ag1+ and three H1+ atoms. All N–H bond lengths are 1.02 Å. In the second N2- site, N2- is bonded in a trigonal non-coplanar geometry to one Ag1+ and three H1+ atoms. All N–H bond lengths are 1.02 Å. In the third N2- site, N2- is bonded in a distorted trigonal non-coplanar geometry to one Ag1+ and three H1+ atoms. There is two shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. In the fourth N2- site, N2- is bonded in a trigonal non-coplanar geometry to one Ag1+ and three H1+ atoms. All N–H bond lengths are 1.02 Å. There are twelve inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the seventh H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the eighth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the ninth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the tenth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the eleventh H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the twelfth H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom.},
doi = {10.17188/1710607},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}