U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on SnH12N3F7 by Materials Project
Abstract
(NH4)3SnF7 crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight tetrafluorostannane;dihydrofluoride molecules and eight N3H12F clusters. In each N3H12F cluster, N3- is bonded in a tetrahedral geometry to four H1+ atoms. There are a spread of N–H bond distances ranging from 1.03–1.07 Å. There are four inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the third H1+ site, H1+ is bonded in a distorted linear geometry to one N3- and one F1- atom. The H–F bond length is 1.54 Å. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. F1- is bonded in a trigonal non-coplanar geometry to three equivalent H1+ atoms.
- Publication Date:
- Other Number(s):
- mp-1195108
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; F-H-N-Sn; SnH12N3F7; crystal structure
- OSTI Identifier:
- 1709146
- DOI:
- https://doi.org/10.17188/1709146
Citation Formats
Materials Data on SnH12N3F7 by Materials Project. United States: N. p., 2019.
Web. doi:10.17188/1709146.
Materials Data on SnH12N3F7 by Materials Project. United States. doi:https://doi.org/10.17188/1709146
2019.
"Materials Data on SnH12N3F7 by Materials Project". United States. doi:https://doi.org/10.17188/1709146. https://www.osti.gov/servlets/purl/1709146. Pub date:Fri Jan 11 23:00:00 EST 2019
@article{osti_1709146,
title = {Materials Data on SnH12N3F7 by Materials Project},
abstractNote = {(NH4)3SnF7 crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight tetrafluorostannane;dihydrofluoride molecules and eight N3H12F clusters. In each N3H12F cluster, N3- is bonded in a tetrahedral geometry to four H1+ atoms. There are a spread of N–H bond distances ranging from 1.03–1.07 Å. There are four inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the third H1+ site, H1+ is bonded in a distorted linear geometry to one N3- and one F1- atom. The H–F bond length is 1.54 Å. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. F1- is bonded in a trigonal non-coplanar geometry to three equivalent H1+ atoms.},
doi = {10.17188/1709146},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}