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Title: Materials Data on SnH12N3F7 by Materials Project

Abstract

(NH4)3SnF7 crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight tetrafluorostannane;dihydrofluoride molecules and eight N3H12F clusters. In each N3H12F cluster, N3- is bonded in a tetrahedral geometry to four H1+ atoms. There are a spread of N–H bond distances ranging from 1.03–1.07 Å. There are four inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the third H1+ site, H1+ is bonded in a distorted linear geometry to one N3- and one F1- atom. The H–F bond length is 1.54 Å. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. F1- is bonded in a trigonal non-coplanar geometry to three equivalent H1+ atoms.

Publication Date:
Other Number(s):
mp-1195108
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; SnH12N3F7; F-H-N-Sn
OSTI Identifier:
1709146
DOI:
https://doi.org/10.17188/1709146

Citation Formats

The Materials Project. Materials Data on SnH12N3F7 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1709146.
The Materials Project. Materials Data on SnH12N3F7 by Materials Project. United States. doi:https://doi.org/10.17188/1709146
The Materials Project. 2019. "Materials Data on SnH12N3F7 by Materials Project". United States. doi:https://doi.org/10.17188/1709146. https://www.osti.gov/servlets/purl/1709146. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1709146,
title = {Materials Data on SnH12N3F7 by Materials Project},
author = {The Materials Project},
abstractNote = {(NH4)3SnF7 crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight tetrafluorostannane;dihydrofluoride molecules and eight N3H12F clusters. In each N3H12F cluster, N3- is bonded in a tetrahedral geometry to four H1+ atoms. There are a spread of N–H bond distances ranging from 1.03–1.07 Å. There are four inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the third H1+ site, H1+ is bonded in a distorted linear geometry to one N3- and one F1- atom. The H–F bond length is 1.54 Å. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. F1- is bonded in a trigonal non-coplanar geometry to three equivalent H1+ atoms.},
doi = {10.17188/1709146},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}