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Title: Materials Data on Fe(CN)3 by Materials Project

Abstract

FeFe(CN)6 is alpha Po structured and crystallizes in the cubic Fm-3m space group. The structure is zero-dimensional and consists of four iron molecules and four Fe(CN)6 clusters. In each Fe(CN)6 cluster, Fe3+ is bonded in an octahedral geometry to six equivalent N3- atoms. All Fe–N bond lengths are 1.88 Å. C2+ is bonded in a distorted single-bond geometry to one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a linear geometry to one Fe3+ and one C2+ atom.

Publication Date:
Other Number(s):
mp-1212746
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Fe(CN)3; C-Fe-N
OSTI Identifier:
1709140
DOI:
https://doi.org/10.17188/1709140

Citation Formats

The Materials Project. Materials Data on Fe(CN)3 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1709140.
The Materials Project. Materials Data on Fe(CN)3 by Materials Project. United States. doi:https://doi.org/10.17188/1709140
The Materials Project. 2019. "Materials Data on Fe(CN)3 by Materials Project". United States. doi:https://doi.org/10.17188/1709140. https://www.osti.gov/servlets/purl/1709140. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1709140,
title = {Materials Data on Fe(CN)3 by Materials Project},
author = {The Materials Project},
abstractNote = {FeFe(CN)6 is alpha Po structured and crystallizes in the cubic Fm-3m space group. The structure is zero-dimensional and consists of four iron molecules and four Fe(CN)6 clusters. In each Fe(CN)6 cluster, Fe3+ is bonded in an octahedral geometry to six equivalent N3- atoms. All Fe–N bond lengths are 1.88 Å. C2+ is bonded in a distorted single-bond geometry to one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a linear geometry to one Fe3+ and one C2+ atom.},
doi = {10.17188/1709140},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}