U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Ce5Sn3 by Materials Project
Abstract
Ce5Sn3 crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. there are two inequivalent Ce sites. In the first Ce site, Ce is bonded to six Sn atoms to form corner-sharing CeSn6 octahedra. The corner-sharing octahedra tilt angles range from 0–52°. There are four shorter (3.28 Å) and two longer (3.41 Å) Ce–Sn bond lengths. In the second Ce site, Ce is bonded in a 5-coordinate geometry to five Sn atoms. There are a spread of Ce–Sn bond distances ranging from 3.16–3.34 Å. There are two inequivalent Sn sites. In the first Sn site, Sn is bonded in a distorted q6 geometry to ten Ce atoms. In the second Sn site, Sn is bonded in a 9-coordinate geometry to eight Ce and one Sn atom. The Sn–Sn bond length is 3.01 Å.
- Publication Date:
- Other Number(s):
- mp-1105948
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Ce-Sn; Ce5Sn3; crystal structure
- OSTI Identifier:
- 1709135
- DOI:
- https://doi.org/10.17188/1709135
Citation Formats
Materials Data on Ce5Sn3 by Materials Project. United States: N. p., 2018.
Web. doi:10.17188/1709135.
Materials Data on Ce5Sn3 by Materials Project. United States. doi:https://doi.org/10.17188/1709135
2018.
"Materials Data on Ce5Sn3 by Materials Project". United States. doi:https://doi.org/10.17188/1709135. https://www.osti.gov/servlets/purl/1709135. Pub date:Thu Jul 19 04:00:00 UTC 2018
@article{osti_1709135,
title = {Materials Data on Ce5Sn3 by Materials Project},
abstractNote = {Ce5Sn3 crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. there are two inequivalent Ce sites. In the first Ce site, Ce is bonded to six Sn atoms to form corner-sharing CeSn6 octahedra. The corner-sharing octahedra tilt angles range from 0–52°. There are four shorter (3.28 Å) and two longer (3.41 Å) Ce–Sn bond lengths. In the second Ce site, Ce is bonded in a 5-coordinate geometry to five Sn atoms. There are a spread of Ce–Sn bond distances ranging from 3.16–3.34 Å. There are two inequivalent Sn sites. In the first Sn site, Sn is bonded in a distorted q6 geometry to ten Ce atoms. In the second Sn site, Sn is bonded in a 9-coordinate geometry to eight Ce and one Sn atom. The Sn–Sn bond length is 3.01 Å.},
doi = {10.17188/1709135},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {7}
}