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Title: Materials Data on Ce5Sn3 by Materials Project

Abstract

Ce5Sn3 crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. there are two inequivalent Ce sites. In the first Ce site, Ce is bonded to six Sn atoms to form corner-sharing CeSn6 octahedra. The corner-sharing octahedra tilt angles range from 0–52°. There are four shorter (3.28 Å) and two longer (3.41 Å) Ce–Sn bond lengths. In the second Ce site, Ce is bonded in a 5-coordinate geometry to five Sn atoms. There are a spread of Ce–Sn bond distances ranging from 3.16–3.34 Å. There are two inequivalent Sn sites. In the first Sn site, Sn is bonded in a distorted q6 geometry to ten Ce atoms. In the second Sn site, Sn is bonded in a 9-coordinate geometry to eight Ce and one Sn atom. The Sn–Sn bond length is 3.01 Å.

Publication Date:
Other Number(s):
mp-1105948
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ce5Sn3; Ce-Sn
OSTI Identifier:
1709135
DOI:
https://doi.org/10.17188/1709135

Citation Formats

The Materials Project. Materials Data on Ce5Sn3 by Materials Project. United States: N. p., 2018. Web. doi:10.17188/1709135.
The Materials Project. Materials Data on Ce5Sn3 by Materials Project. United States. doi:https://doi.org/10.17188/1709135
The Materials Project. 2018. "Materials Data on Ce5Sn3 by Materials Project". United States. doi:https://doi.org/10.17188/1709135. https://www.osti.gov/servlets/purl/1709135. Pub date:Thu Jul 19 00:00:00 EDT 2018
@article{osti_1709135,
title = {Materials Data on Ce5Sn3 by Materials Project},
author = {The Materials Project},
abstractNote = {Ce5Sn3 crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. there are two inequivalent Ce sites. In the first Ce site, Ce is bonded to six Sn atoms to form corner-sharing CeSn6 octahedra. The corner-sharing octahedra tilt angles range from 0–52°. There are four shorter (3.28 Å) and two longer (3.41 Å) Ce–Sn bond lengths. In the second Ce site, Ce is bonded in a 5-coordinate geometry to five Sn atoms. There are a spread of Ce–Sn bond distances ranging from 3.16–3.34 Å. There are two inequivalent Sn sites. In the first Sn site, Sn is bonded in a distorted q6 geometry to ten Ce atoms. In the second Sn site, Sn is bonded in a 9-coordinate geometry to eight Ce and one Sn atom. The Sn–Sn bond length is 3.01 Å.},
doi = {10.17188/1709135},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {7}
}