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Title: Materials Data on Ce4SnO10 by Materials Project

Abstract

Ce4SnO10 is Fluorite-derived structured and crystallizes in the orthorhombic Immm space group. The structure is three-dimensional. there are two inequivalent Ce4+ sites. In the first Ce4+ site, Ce4+ is bonded in a body-centered cubic geometry to eight O2- atoms. There are four shorter (2.36 Å) and four longer (2.37 Å) Ce–O bond lengths. In the second Ce4+ site, Ce4+ is bonded in a body-centered cubic geometry to eight O2- atoms. There are a spread of Ce–O bond distances ranging from 2.34–2.39 Å. Sn4+ is bonded in a body-centered cubic geometry to eight O2- atoms. There are four shorter (2.25 Å) and four longer (2.29 Å) Sn–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded to four Ce4+ atoms to form a mixture of edge and corner-sharing OCe4 tetrahedra. In the second O2- site, O2- is bonded to three Ce4+ and one Sn4+ atom to form a mixture of edge and corner-sharing OCe3Sn tetrahedra. In the third O2- site, O2- is bonded to two equivalent Ce4+ and two equivalent Sn4+ atoms to form OCe2Sn2 tetrahedra that share corners with sixteen OCe4 tetrahedra and edges with six OCe3Sn tetrahedra.

Publication Date:
Other Number(s):
mp-1226901
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ce4SnO10; Ce-O-Sn
OSTI Identifier:
1706806
DOI:
https://doi.org/10.17188/1706806

Citation Formats

The Materials Project. Materials Data on Ce4SnO10 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1706806.
The Materials Project. Materials Data on Ce4SnO10 by Materials Project. United States. doi:https://doi.org/10.17188/1706806
The Materials Project. 2020. "Materials Data on Ce4SnO10 by Materials Project". United States. doi:https://doi.org/10.17188/1706806. https://www.osti.gov/servlets/purl/1706806. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1706806,
title = {Materials Data on Ce4SnO10 by Materials Project},
author = {The Materials Project},
abstractNote = {Ce4SnO10 is Fluorite-derived structured and crystallizes in the orthorhombic Immm space group. The structure is three-dimensional. there are two inequivalent Ce4+ sites. In the first Ce4+ site, Ce4+ is bonded in a body-centered cubic geometry to eight O2- atoms. There are four shorter (2.36 Å) and four longer (2.37 Å) Ce–O bond lengths. In the second Ce4+ site, Ce4+ is bonded in a body-centered cubic geometry to eight O2- atoms. There are a spread of Ce–O bond distances ranging from 2.34–2.39 Å. Sn4+ is bonded in a body-centered cubic geometry to eight O2- atoms. There are four shorter (2.25 Å) and four longer (2.29 Å) Sn–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded to four Ce4+ atoms to form a mixture of edge and corner-sharing OCe4 tetrahedra. In the second O2- site, O2- is bonded to three Ce4+ and one Sn4+ atom to form a mixture of edge and corner-sharing OCe3Sn tetrahedra. In the third O2- site, O2- is bonded to two equivalent Ce4+ and two equivalent Sn4+ atoms to form OCe2Sn2 tetrahedra that share corners with sixteen OCe4 tetrahedra and edges with six OCe3Sn tetrahedra.},
doi = {10.17188/1706806},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}