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Title: Materials Data on VN3O8 by Materials Project

Abstract

(VO8)2(N2)3 crystallizes in the tetragonal I-42m space group. The structure is zero-dimensional and consists of six ammonia molecules and two VO8 clusters. In each VO8 cluster, V5+ is bonded in a hexagonal bipyramidal geometry to eight O2- atoms. There is four shorter (1.94 Å) and four longer (1.97 Å) V–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 1-coordinate geometry to one V5+ and one O2- atom. The O–O bond length is 1.36 Å. In the second O2- site, O2- is bonded in a 1-coordinate geometry to one V5+ and one O2- atom.

Authors:
Publication Date:
Other Number(s):
mp-1207836
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; VN3O8; N-O-V
OSTI Identifier:
1705740
DOI:
https://doi.org/10.17188/1705740

Citation Formats

The Materials Project. Materials Data on VN3O8 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1705740.
The Materials Project. Materials Data on VN3O8 by Materials Project. United States. doi:https://doi.org/10.17188/1705740
The Materials Project. 2020. "Materials Data on VN3O8 by Materials Project". United States. doi:https://doi.org/10.17188/1705740. https://www.osti.gov/servlets/purl/1705740. Pub date:Sun May 03 00:00:00 EDT 2020
@article{osti_1705740,
title = {Materials Data on VN3O8 by Materials Project},
author = {The Materials Project},
abstractNote = {(VO8)2(N2)3 crystallizes in the tetragonal I-42m space group. The structure is zero-dimensional and consists of six ammonia molecules and two VO8 clusters. In each VO8 cluster, V5+ is bonded in a hexagonal bipyramidal geometry to eight O2- atoms. There is four shorter (1.94 Å) and four longer (1.97 Å) V–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 1-coordinate geometry to one V5+ and one O2- atom. The O–O bond length is 1.36 Å. In the second O2- site, O2- is bonded in a 1-coordinate geometry to one V5+ and one O2- atom.},
doi = {10.17188/1705740},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}