U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Mn4Cu3BiO12 by Materials Project
Abstract
BiCu3Mn4O12 crystallizes in the cubic Im-3 space group. The structure is three-dimensional. Mn+4.50+ is bonded to six equivalent O2- atoms to form MnO6 octahedra that share corners with six equivalent MnO6 octahedra and faces with two equivalent BiO12 cuboctahedra. The corner-sharing octahedral tilt angles are 43°. All Mn–O bond lengths are 2.00 Å. Cu1+ is bonded in a square co-planar geometry to four equivalent O2- atoms. All Cu–O bond lengths are 1.92 Å. Bi3+ is bonded to twelve equivalent O2- atoms to form BiO12 cuboctahedra that share faces with eight equivalent MnO6 octahedra. All Bi–O bond lengths are 2.63 Å. O2- is bonded in a 3-coordinate geometry to two equivalent Mn+4.50+, one Cu1+, and one Bi3+ atom.
- Publication Date:
- Other Number(s):
- mp-1210616
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Bi-Cu-Mn-O; Mn4Cu3BiO12; crystal structure
- OSTI Identifier:
- 1704974
- DOI:
- https://doi.org/10.17188/1704974
Citation Formats
Materials Data on Mn4Cu3BiO12 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1704974.
Materials Data on Mn4Cu3BiO12 by Materials Project. United States. doi:https://doi.org/10.17188/1704974
2020.
"Materials Data on Mn4Cu3BiO12 by Materials Project". United States. doi:https://doi.org/10.17188/1704974. https://www.osti.gov/servlets/purl/1704974. Pub date:Thu Jun 04 04:00:00 UTC 2020
@article{osti_1704974,
title = {Materials Data on Mn4Cu3BiO12 by Materials Project},
abstractNote = {BiCu3Mn4O12 crystallizes in the cubic Im-3 space group. The structure is three-dimensional. Mn+4.50+ is bonded to six equivalent O2- atoms to form MnO6 octahedra that share corners with six equivalent MnO6 octahedra and faces with two equivalent BiO12 cuboctahedra. The corner-sharing octahedral tilt angles are 43°. All Mn–O bond lengths are 2.00 Å. Cu1+ is bonded in a square co-planar geometry to four equivalent O2- atoms. All Cu–O bond lengths are 1.92 Å. Bi3+ is bonded to twelve equivalent O2- atoms to form BiO12 cuboctahedra that share faces with eight equivalent MnO6 octahedra. All Bi–O bond lengths are 2.63 Å. O2- is bonded in a 3-coordinate geometry to two equivalent Mn+4.50+, one Cu1+, and one Bi3+ atom.},
doi = {10.17188/1704974},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {6}
}
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