U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on SiAg5O4 by Materials Project
Abstract
Ag5SiO4 crystallizes in the orthorhombic Pnnm space group. The structure is three-dimensional. there are three inequivalent Ag+2.40+ sites. In the first Ag+2.40+ site, Ag+2.40+ is bonded in a rectangular see-saw-like geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.35–2.79 Å. In the second Ag+2.40+ site, Ag+2.40+ is bonded in a distorted T-shaped geometry to three O2- atoms. There are a spread of Ag–O bond distances ranging from 2.39–2.52 Å. In the third Ag+2.40+ site, Ag+2.40+ is bonded in a water-like geometry to two equivalent O2- atoms. Both Ag–O bond lengths are 2.36 Å. Si4- is bonded in a tetrahedral geometry to four O2- atoms. There is one shorter (1.66 Å) and three longer (1.67 Å) Si–O bond length. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 1-coordinate geometry to four Ag+2.40+ and one Si4- atom. In the second O2- site, O2- is bonded in a 1-coordinate geometry to four Ag+2.40+ and one Si4- atom. In the third O2- site, O2- is bonded in a 1-coordinate geometry to four Ag+2.40+ and one Si4- atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1205049
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; SiAg5O4; Ag-O-Si
- OSTI Identifier:
- 1704921
- DOI:
- https://doi.org/10.17188/1704921
Citation Formats
The Materials Project. Materials Data on SiAg5O4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1704921.
The Materials Project. Materials Data on SiAg5O4 by Materials Project. United States. doi:https://doi.org/10.17188/1704921
The Materials Project. 2020.
"Materials Data on SiAg5O4 by Materials Project". United States. doi:https://doi.org/10.17188/1704921. https://www.osti.gov/servlets/purl/1704921. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1704921,
title = {Materials Data on SiAg5O4 by Materials Project},
author = {The Materials Project},
abstractNote = {Ag5SiO4 crystallizes in the orthorhombic Pnnm space group. The structure is three-dimensional. there are three inequivalent Ag+2.40+ sites. In the first Ag+2.40+ site, Ag+2.40+ is bonded in a rectangular see-saw-like geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.35–2.79 Å. In the second Ag+2.40+ site, Ag+2.40+ is bonded in a distorted T-shaped geometry to three O2- atoms. There are a spread of Ag–O bond distances ranging from 2.39–2.52 Å. In the third Ag+2.40+ site, Ag+2.40+ is bonded in a water-like geometry to two equivalent O2- atoms. Both Ag–O bond lengths are 2.36 Å. Si4- is bonded in a tetrahedral geometry to four O2- atoms. There is one shorter (1.66 Å) and three longer (1.67 Å) Si–O bond length. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 1-coordinate geometry to four Ag+2.40+ and one Si4- atom. In the second O2- site, O2- is bonded in a 1-coordinate geometry to four Ag+2.40+ and one Si4- atom. In the third O2- site, O2- is bonded in a 1-coordinate geometry to four Ag+2.40+ and one Si4- atom.},
doi = {10.17188/1704921},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}