U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on VCoP by Materials Project
Abstract
VCoP crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. V2+ is bonded to five equivalent P3- atoms to form distorted VP5 trigonal bipyramids that share corners with eight equivalent CoP4 tetrahedra, corners with eight equivalent VP5 trigonal bipyramids, edges with six equivalent CoP4 tetrahedra, and edges with six equivalent VP5 trigonal bipyramids. There are a spread of V–P bond distances ranging from 2.42–2.53 Å. Co1+ is bonded to four equivalent P3- atoms to form CoP4 tetrahedra that share corners with eight equivalent CoP4 tetrahedra, corners with eight equivalent VP5 trigonal bipyramids, edges with two equivalent CoP4 tetrahedra, and edges with six equivalent VP5 trigonal bipyramids. There are three shorter (2.22 Å) and one longer (2.25 Å) Co–P bond lengths. P3- is bonded in a 9-coordinate geometry to five equivalent V2+ and four equivalent Co1+ atoms.
- Publication Date:
- Other Number(s):
- mp-1101982
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Co-P-V; VCoP; crystal structure
- OSTI Identifier:
- 1700425
- DOI:
- https://doi.org/10.17188/1700425
Citation Formats
Materials Data on VCoP by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1700425.
Materials Data on VCoP by Materials Project. United States. doi:https://doi.org/10.17188/1700425
2020.
"Materials Data on VCoP by Materials Project". United States. doi:https://doi.org/10.17188/1700425. https://www.osti.gov/servlets/purl/1700425. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1700425,
title = {Materials Data on VCoP by Materials Project},
abstractNote = {VCoP crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. V2+ is bonded to five equivalent P3- atoms to form distorted VP5 trigonal bipyramids that share corners with eight equivalent CoP4 tetrahedra, corners with eight equivalent VP5 trigonal bipyramids, edges with six equivalent CoP4 tetrahedra, and edges with six equivalent VP5 trigonal bipyramids. There are a spread of V–P bond distances ranging from 2.42–2.53 Å. Co1+ is bonded to four equivalent P3- atoms to form CoP4 tetrahedra that share corners with eight equivalent CoP4 tetrahedra, corners with eight equivalent VP5 trigonal bipyramids, edges with two equivalent CoP4 tetrahedra, and edges with six equivalent VP5 trigonal bipyramids. There are three shorter (2.22 Å) and one longer (2.25 Å) Co–P bond lengths. P3- is bonded in a 9-coordinate geometry to five equivalent V2+ and four equivalent Co1+ atoms.},
doi = {10.17188/1700425},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}