U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Rb2LaF5 by Materials Project
Abstract
Rb2LaF5 crystallizes in the orthorhombic Pna2_1 space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Rb–F bond distances ranging from 2.85–3.07 Å. In the second Rb1+ site, Rb1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Rb–F bond distances ranging from 2.87–3.18 Å. La3+ is bonded to seven F1- atoms to form distorted edge-sharing LaF7 pentagonal bipyramids. There are a spread of La–F bond distances ranging from 2.34–2.47 Å. There are five inequivalent F1- sites. In the first F1- site, F1- is bonded in a 4-coordinate geometry to two Rb1+ and two equivalent La3+ atoms. In the second F1- site, F1- is bonded in a 5-coordinate geometry to four Rb1+ and one La3+ atom. In the third F1- site, F1- is bonded in a 4-coordinate geometry to two Rb1+ and two equivalent La3+ atoms. In the fourth F1- site, F1- is bonded in a 5-coordinate geometry to four Rb1+ and one La3+ atom. In the fifth F1- site, F1- is bonded in a 1-coordinate geometry to four Rb1+ andmore »
- Publication Date:
- Other Number(s):
- mp-1209616
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; F-La-Rb; Rb2LaF5; crystal structure
- OSTI Identifier:
- 1699869
- DOI:
- https://doi.org/10.17188/1699869
Citation Formats
Materials Data on Rb2LaF5 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1699869.
Materials Data on Rb2LaF5 by Materials Project. United States. doi:https://doi.org/10.17188/1699869
2020.
"Materials Data on Rb2LaF5 by Materials Project". United States. doi:https://doi.org/10.17188/1699869. https://www.osti.gov/servlets/purl/1699869. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1699869,
title = {Materials Data on Rb2LaF5 by Materials Project},
abstractNote = {Rb2LaF5 crystallizes in the orthorhombic Pna2_1 space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Rb–F bond distances ranging from 2.85–3.07 Å. In the second Rb1+ site, Rb1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Rb–F bond distances ranging from 2.87–3.18 Å. La3+ is bonded to seven F1- atoms to form distorted edge-sharing LaF7 pentagonal bipyramids. There are a spread of La–F bond distances ranging from 2.34–2.47 Å. There are five inequivalent F1- sites. In the first F1- site, F1- is bonded in a 4-coordinate geometry to two Rb1+ and two equivalent La3+ atoms. In the second F1- site, F1- is bonded in a 5-coordinate geometry to four Rb1+ and one La3+ atom. In the third F1- site, F1- is bonded in a 4-coordinate geometry to two Rb1+ and two equivalent La3+ atoms. In the fourth F1- site, F1- is bonded in a 5-coordinate geometry to four Rb1+ and one La3+ atom. In the fifth F1- site, F1- is bonded in a 1-coordinate geometry to four Rb1+ and one La3+ atom.},
doi = {10.17188/1699869},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}