U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Sm3Zn11 by Materials Project
Abstract
Sm3Zn11 crystallizes in the orthorhombic Immm space group. The structure is three-dimensional. there are two inequivalent Sm sites. In the first Sm site, Sm is bonded in a 12-coordinate geometry to sixteen Zn atoms. There are a spread of Sm–Zn bond distances ranging from 3.09–3.55 Å. In the second Sm site, Sm is bonded in a 10-coordinate geometry to sixteen Zn atoms. There are a spread of Sm–Zn bond distances ranging from 3.09–3.43 Å. There are four inequivalent Zn sites. In the first Zn site, Zn is bonded to four equivalent Sm and eight Zn atoms to form face-sharing ZnSm4Zn8 cuboctahedra. There are four shorter (2.69 Å) and four longer (2.81 Å) Zn–Zn bond lengths. In the second Zn site, Zn is bonded to four Sm and eight Zn atoms to form a mixture of distorted face, edge, and corner-sharing ZnSm4Zn8 cuboctahedra. There are two shorter (2.59 Å) and four longer (2.88 Å) Zn–Zn bond lengths. In the third Zn site, Zn is bonded in a 10-coordinate geometry to five Sm and five Zn atoms. There are a spread of Zn–Zn bond distances ranging from 2.49–2.73 Å. In the fourth Zn site, Zn is bonded in a 10-coordinate geometry tomore »
- Publication Date:
- Other Number(s):
- mp-1103573
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Sm-Zn; Sm3Zn11; crystal structure
- OSTI Identifier:
- 1699290
- DOI:
- https://doi.org/10.17188/1699290
Citation Formats
Materials Data on Sm3Zn11 by Materials Project. United States: N. p., 2018.
Web. doi:10.17188/1699290.
Materials Data on Sm3Zn11 by Materials Project. United States. doi:https://doi.org/10.17188/1699290
2018.
"Materials Data on Sm3Zn11 by Materials Project". United States. doi:https://doi.org/10.17188/1699290. https://www.osti.gov/servlets/purl/1699290. Pub date:Wed Jul 18 04:00:00 UTC 2018
@article{osti_1699290,
title = {Materials Data on Sm3Zn11 by Materials Project},
abstractNote = {Sm3Zn11 crystallizes in the orthorhombic Immm space group. The structure is three-dimensional. there are two inequivalent Sm sites. In the first Sm site, Sm is bonded in a 12-coordinate geometry to sixteen Zn atoms. There are a spread of Sm–Zn bond distances ranging from 3.09–3.55 Å. In the second Sm site, Sm is bonded in a 10-coordinate geometry to sixteen Zn atoms. There are a spread of Sm–Zn bond distances ranging from 3.09–3.43 Å. There are four inequivalent Zn sites. In the first Zn site, Zn is bonded to four equivalent Sm and eight Zn atoms to form face-sharing ZnSm4Zn8 cuboctahedra. There are four shorter (2.69 Å) and four longer (2.81 Å) Zn–Zn bond lengths. In the second Zn site, Zn is bonded to four Sm and eight Zn atoms to form a mixture of distorted face, edge, and corner-sharing ZnSm4Zn8 cuboctahedra. There are two shorter (2.59 Å) and four longer (2.88 Å) Zn–Zn bond lengths. In the third Zn site, Zn is bonded in a 10-coordinate geometry to five Sm and five Zn atoms. There are a spread of Zn–Zn bond distances ranging from 2.49–2.73 Å. In the fourth Zn site, Zn is bonded in a 10-coordinate geometry to four Sm and six Zn atoms.},
doi = {10.17188/1699290},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {7}
}