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Title: Materials Data on NaSbO7 by Materials Project

Abstract

NaSbO5O2 crystallizes in the orthorhombic Cmc2_1 space group. The structure is three-dimensional and consists of four hydrogen peroxide molecules and one NaSbO5 framework. In the NaSbO5 framework, Na is bonded in a 4-coordinate geometry to four equivalent O atoms. There are two shorter (2.41 Å) and two longer (2.69 Å) Na–O bond lengths. Sb is bonded in a 5-coordinate geometry to five O atoms. There are a spread of Sb–O bond distances ranging from 1.87–2.45 Å. There are three inequivalent O sites. In the first O site, O is bonded in a distorted trigonal non-coplanar geometry to one Sb and two equivalent O atoms. Both O–O bond lengths are 1.46 Å. In the second O site, O is bonded in a 3-coordinate geometry to two equivalent Na and one Sb atom. In the third O site, O is bonded in an L-shaped geometry to one Sb and one O atom.

Authors:
Publication Date:
Other Number(s):
mp-1180855
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; NaSbO7; Na-O-Sb
OSTI Identifier:
1698613
DOI:
https://doi.org/10.17188/1698613

Citation Formats

The Materials Project. Materials Data on NaSbO7 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1698613.
The Materials Project. Materials Data on NaSbO7 by Materials Project. United States. doi:https://doi.org/10.17188/1698613
The Materials Project. 2020. "Materials Data on NaSbO7 by Materials Project". United States. doi:https://doi.org/10.17188/1698613. https://www.osti.gov/servlets/purl/1698613. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1698613,
title = {Materials Data on NaSbO7 by Materials Project},
author = {The Materials Project},
abstractNote = {NaSbO5O2 crystallizes in the orthorhombic Cmc2_1 space group. The structure is three-dimensional and consists of four hydrogen peroxide molecules and one NaSbO5 framework. In the NaSbO5 framework, Na is bonded in a 4-coordinate geometry to four equivalent O atoms. There are two shorter (2.41 Å) and two longer (2.69 Å) Na–O bond lengths. Sb is bonded in a 5-coordinate geometry to five O atoms. There are a spread of Sb–O bond distances ranging from 1.87–2.45 Å. There are three inequivalent O sites. In the first O site, O is bonded in a distorted trigonal non-coplanar geometry to one Sb and two equivalent O atoms. Both O–O bond lengths are 1.46 Å. In the second O site, O is bonded in a 3-coordinate geometry to two equivalent Na and one Sb atom. In the third O site, O is bonded in an L-shaped geometry to one Sb and one O atom.},
doi = {10.17188/1698613},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}