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Title: Materials Data on Eu(BH4)2 by Materials Project

Abstract

Eu(BH4)2 crystallizes in the orthorhombic Pbcn space group. The structure is three-dimensional. Eu2+ is bonded in a 2-coordinate geometry to ten H+0.50+ atoms. There are a spread of Eu–H bond distances ranging from 2.44–2.69 Å. B3- is bonded in a tetrahedral geometry to four H+0.50+ atoms. All B–H bond lengths are 1.23 Å. There are four inequivalent H+0.50+ sites. In the first H+0.50+ site, H+0.50+ is bonded in a distorted single-bond geometry to two equivalent Eu2+ and one B3- atom. In the second H+0.50+ site, H+0.50+ is bonded in a single-bond geometry to one Eu2+ and one B3- atom. In the third H+0.50+ site, H+0.50+ is bonded in a single-bond geometry to one Eu2+ and one B3- atom. In the fourth H+0.50+ site, H+0.50+ is bonded in a single-bond geometry to one Eu2+ and one B3- atom.

Authors:
Publication Date:
Other Number(s):
mp-1195232
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Eu(BH4)2; B-Eu-H
OSTI Identifier:
1698578
DOI:
https://doi.org/10.17188/1698578

Citation Formats

The Materials Project. Materials Data on Eu(BH4)2 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1698578.
The Materials Project. Materials Data on Eu(BH4)2 by Materials Project. United States. doi:https://doi.org/10.17188/1698578
The Materials Project. 2019. "Materials Data on Eu(BH4)2 by Materials Project". United States. doi:https://doi.org/10.17188/1698578. https://www.osti.gov/servlets/purl/1698578. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1698578,
title = {Materials Data on Eu(BH4)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Eu(BH4)2 crystallizes in the orthorhombic Pbcn space group. The structure is three-dimensional. Eu2+ is bonded in a 2-coordinate geometry to ten H+0.50+ atoms. There are a spread of Eu–H bond distances ranging from 2.44–2.69 Å. B3- is bonded in a tetrahedral geometry to four H+0.50+ atoms. All B–H bond lengths are 1.23 Å. There are four inequivalent H+0.50+ sites. In the first H+0.50+ site, H+0.50+ is bonded in a distorted single-bond geometry to two equivalent Eu2+ and one B3- atom. In the second H+0.50+ site, H+0.50+ is bonded in a single-bond geometry to one Eu2+ and one B3- atom. In the third H+0.50+ site, H+0.50+ is bonded in a single-bond geometry to one Eu2+ and one B3- atom. In the fourth H+0.50+ site, H+0.50+ is bonded in a single-bond geometry to one Eu2+ and one B3- atom.},
doi = {10.17188/1698578},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}