U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on FeH10S2(NO2)4 by Materials Project
Abstract
Fe(SO4)2(NH2)2(NH3)2 crystallizes in the triclinic P-1 space group. The structure is one-dimensional and consists of two ammonia molecules; two ammonia molecules; and one Fe(SO4)2 ribbon oriented in the (1, 0, 0) direction. In the Fe(SO4)2 ribbon, Fe2+ is bonded in a square co-planar geometry to four O2- atoms. There are two shorter (2.12 Å) and two longer (2.20 Å) Fe–O bond lengths. S2- is bonded in a tetrahedral geometry to four O2- atoms. There are a spread of S–O bond distances ranging from 1.48–1.50 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 150 degrees geometry to one Fe2+ and one S2- atom. In the second O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Fe2+ and one S2- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one S2- atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one S2- atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1191501
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; FeH10S2(NO2)4; Fe-H-N-O-S
- OSTI Identifier:
- 1694741
- DOI:
- https://doi.org/10.17188/1694741
Citation Formats
The Materials Project. Materials Data on FeH10S2(NO2)4 by Materials Project. United States: N. p., 2019.
Web. doi:10.17188/1694741.
The Materials Project. Materials Data on FeH10S2(NO2)4 by Materials Project. United States. doi:https://doi.org/10.17188/1694741
The Materials Project. 2019.
"Materials Data on FeH10S2(NO2)4 by Materials Project". United States. doi:https://doi.org/10.17188/1694741. https://www.osti.gov/servlets/purl/1694741. Pub date:Fri Jan 11 00:00:00 EST 2019
@article{osti_1694741,
title = {Materials Data on FeH10S2(NO2)4 by Materials Project},
author = {The Materials Project},
abstractNote = {Fe(SO4)2(NH2)2(NH3)2 crystallizes in the triclinic P-1 space group. The structure is one-dimensional and consists of two ammonia molecules; two ammonia molecules; and one Fe(SO4)2 ribbon oriented in the (1, 0, 0) direction. In the Fe(SO4)2 ribbon, Fe2+ is bonded in a square co-planar geometry to four O2- atoms. There are two shorter (2.12 Å) and two longer (2.20 Å) Fe–O bond lengths. S2- is bonded in a tetrahedral geometry to four O2- atoms. There are a spread of S–O bond distances ranging from 1.48–1.50 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 150 degrees geometry to one Fe2+ and one S2- atom. In the second O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Fe2+ and one S2- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one S2- atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one S2- atom.},
doi = {10.17188/1694741},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}