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Title: Materials Data on U(NO4)2 by Materials Project

Abstract

UO2(NO3)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one hydrogen peroxide molecule and one U(NO3)2 cluster. In the U(NO3)2 cluster, U6+ is bonded in a square co-planar geometry to four O2- atoms. There are two shorter (1.79 Å) and two longer (2.28 Å) U–O bond lengths. N5+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.21 Å) and one longer (1.34 Å) N–O bond length. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 120 degrees geometry to one U6+ and one N5+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one N5+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one U6+ atom.

Authors:
Publication Date:
Other Number(s):
mp-1103907
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; U(NO4)2; N-O-U
OSTI Identifier:
1692808
DOI:
https://doi.org/10.17188/1692808

Citation Formats

The Materials Project. Materials Data on U(NO4)2 by Materials Project. United States: N. p., 2018. Web. doi:10.17188/1692808.
The Materials Project. Materials Data on U(NO4)2 by Materials Project. United States. doi:https://doi.org/10.17188/1692808
The Materials Project. 2018. "Materials Data on U(NO4)2 by Materials Project". United States. doi:https://doi.org/10.17188/1692808. https://www.osti.gov/servlets/purl/1692808. Pub date:Wed Jul 18 00:00:00 EDT 2018
@article{osti_1692808,
title = {Materials Data on U(NO4)2 by Materials Project},
author = {The Materials Project},
abstractNote = {UO2(NO3)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one hydrogen peroxide molecule and one U(NO3)2 cluster. In the U(NO3)2 cluster, U6+ is bonded in a square co-planar geometry to four O2- atoms. There are two shorter (1.79 Å) and two longer (2.28 Å) U–O bond lengths. N5+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.21 Å) and one longer (1.34 Å) N–O bond length. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 120 degrees geometry to one U6+ and one N5+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one N5+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one U6+ atom.},
doi = {10.17188/1692808},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {7}
}