DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on Re2Pt(NO2)4 by Materials Project

Abstract

Re2Pt(NO2)4 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Re2Pt(NO2)4 cluster. Re7+ is bonded in a tetrahedral geometry to four O2- atoms. There is three shorter (1.73 Å) and one longer (1.97 Å) Re–O bond length. Pt6+ is bonded in a square co-planar geometry to four N1- atoms. There is two shorter (1.81 Å) and two longer (2.03 Å) Pt–N bond length. There are two inequivalent N1- sites. In the first N1- site, N1- is bonded in a distorted single-bond geometry to one Pt6+ atom. In the second N1- site, N1- is bonded in a distorted bent 120 degrees geometry to one Pt6+ and one O2- atom. The N–O bond length is 1.30 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Re7+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one Re7+ atom. In the third O2- site, O2- is bonded in a bent 120 degrees geometry to one Re7+ and one N1- atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one Re7+ atom.

Authors:
Publication Date:
Other Number(s):
mp-1104080
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Re2Pt(NO2)4; N-O-Pt-Re
OSTI Identifier:
1689343
DOI:
https://doi.org/10.17188/1689343

Citation Formats

The Materials Project. Materials Data on Re2Pt(NO2)4 by Materials Project. United States: N. p., 2018. Web. doi:10.17188/1689343.
The Materials Project. Materials Data on Re2Pt(NO2)4 by Materials Project. United States. doi:https://doi.org/10.17188/1689343
The Materials Project. 2018. "Materials Data on Re2Pt(NO2)4 by Materials Project". United States. doi:https://doi.org/10.17188/1689343. https://www.osti.gov/servlets/purl/1689343. Pub date:Wed Jul 18 00:00:00 EDT 2018
@article{osti_1689343,
title = {Materials Data on Re2Pt(NO2)4 by Materials Project},
author = {The Materials Project},
abstractNote = {Re2Pt(NO2)4 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Re2Pt(NO2)4 cluster. Re7+ is bonded in a tetrahedral geometry to four O2- atoms. There is three shorter (1.73 Å) and one longer (1.97 Å) Re–O bond length. Pt6+ is bonded in a square co-planar geometry to four N1- atoms. There is two shorter (1.81 Å) and two longer (2.03 Å) Pt–N bond length. There are two inequivalent N1- sites. In the first N1- site, N1- is bonded in a distorted single-bond geometry to one Pt6+ atom. In the second N1- site, N1- is bonded in a distorted bent 120 degrees geometry to one Pt6+ and one O2- atom. The N–O bond length is 1.30 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Re7+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one Re7+ atom. In the third O2- site, O2- is bonded in a bent 120 degrees geometry to one Re7+ and one N1- atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one Re7+ atom.},
doi = {10.17188/1689343},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {7}
}