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Title: Materials Data on RbCuAg2(CN)4 by Materials Project

Abstract

RbAg2Cu(CN)4 crystallizes in the monoclinic P2/c space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight N3- atoms. There are a spread of Rb–N bond distances ranging from 3.24–3.34 Å. There are two inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a linear geometry to two equivalent C2+ atoms. Both Ag–C bond lengths are 2.06 Å. In the second Ag1+ site, Ag1+ is bonded in a linear geometry to two equivalent C2+ atoms. Both Ag–C bond lengths are 2.07 Å. Cu1+ is bonded in a tetrahedral geometry to four N3- atoms. There is two shorter (1.97 Å) and two longer (1.99 Å) Cu–N bond length. There are two inequivalent C2+ sites. In the first C2+ site, C2+ is bonded in a linear geometry to one Ag1+ and one N3- atom. The C–N bond length is 1.18 Å. In the second C2+ site, C2+ is bonded in a linear geometry to one Ag1+ and one N3- atom. The C–N bond length is 1.18 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted linear geometry to two equivalent Rb1+, one Cu1+, and one C2+more » atom. In the second N3- site, N3- is bonded in a distorted bent 150 degrees geometry to two equivalent Rb1+, one Cu1+, and one C2+ atom.« less

Publication Date:
Other Number(s):
mp-1192412
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; RbCuAg2(CN)4; Ag-C-Cu-N-Rb
OSTI Identifier:
1686376
DOI:
https://doi.org/10.17188/1686376

Citation Formats

The Materials Project. Materials Data on RbCuAg2(CN)4 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1686376.
The Materials Project. Materials Data on RbCuAg2(CN)4 by Materials Project. United States. doi:https://doi.org/10.17188/1686376
The Materials Project. 2019. "Materials Data on RbCuAg2(CN)4 by Materials Project". United States. doi:https://doi.org/10.17188/1686376. https://www.osti.gov/servlets/purl/1686376. Pub date:Fri Jan 11 00:00:00 EST 2019
@article{osti_1686376,
title = {Materials Data on RbCuAg2(CN)4 by Materials Project},
author = {The Materials Project},
abstractNote = {RbAg2Cu(CN)4 crystallizes in the monoclinic P2/c space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight N3- atoms. There are a spread of Rb–N bond distances ranging from 3.24–3.34 Å. There are two inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a linear geometry to two equivalent C2+ atoms. Both Ag–C bond lengths are 2.06 Å. In the second Ag1+ site, Ag1+ is bonded in a linear geometry to two equivalent C2+ atoms. Both Ag–C bond lengths are 2.07 Å. Cu1+ is bonded in a tetrahedral geometry to four N3- atoms. There is two shorter (1.97 Å) and two longer (1.99 Å) Cu–N bond length. There are two inequivalent C2+ sites. In the first C2+ site, C2+ is bonded in a linear geometry to one Ag1+ and one N3- atom. The C–N bond length is 1.18 Å. In the second C2+ site, C2+ is bonded in a linear geometry to one Ag1+ and one N3- atom. The C–N bond length is 1.18 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted linear geometry to two equivalent Rb1+, one Cu1+, and one C2+ atom. In the second N3- site, N3- is bonded in a distorted bent 150 degrees geometry to two equivalent Rb1+, one Cu1+, and one C2+ atom.},
doi = {10.17188/1686376},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}