U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Tb7RhBr12 by Materials Project
Abstract
Tb7RhBr12 is trigonal omega-derived structured and crystallizes in the trigonal R-3 space group. The structure is three-dimensional. there are two inequivalent Tb sites. In the first Tb site, Tb is bonded to one Rh and five Br atoms to form a mixture of corner and edge-sharing TbRhBr5 octahedra. The corner-sharing octahedra tilt angles range from 0–3°. The Tb–Rh bond length is 2.68 Å. There are a spread of Tb–Br bond distances ranging from 2.91–3.14 Å. In the second Tb site, Tb is bonded to six equivalent Br atoms to form edge-sharing TbBr6 octahedra. All Tb–Br bond lengths are 2.83 Å. Rh is bonded in an octahedral geometry to six equivalent Tb atoms. There are two inequivalent Br sites. In the first Br site, Br is bonded in a T-shaped geometry to three equivalent Tb atoms. In the second Br site, Br is bonded in a distorted T-shaped geometry to three Tb atoms.
- Publication Date:
- Other Number(s):
- mp-1189645
- DOE Contract Number:
- AC02-05CH11231;
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Br-Rh-Tb; crystal structure; Tb7RhBr12
- OSTI Identifier:
- 1685740
- DOI:
- https://doi.org/10.17188/1685740
Citation Formats
Materials Data on Tb7RhBr12 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1685740.
Materials Data on Tb7RhBr12 by Materials Project. United States. doi:https://doi.org/10.17188/1685740
2020.
"Materials Data on Tb7RhBr12 by Materials Project". United States. doi:https://doi.org/10.17188/1685740. https://www.osti.gov/servlets/purl/1685740. Pub date:Fri May 01 20:00:00 EDT 2020
@article{osti_1685740,
title = {Materials Data on Tb7RhBr12 by Materials Project},
abstractNote = {Tb7RhBr12 is trigonal omega-derived structured and crystallizes in the trigonal R-3 space group. The structure is three-dimensional. there are two inequivalent Tb sites. In the first Tb site, Tb is bonded to one Rh and five Br atoms to form a mixture of corner and edge-sharing TbRhBr5 octahedra. The corner-sharing octahedra tilt angles range from 0–3°. The Tb–Rh bond length is 2.68 Å. There are a spread of Tb–Br bond distances ranging from 2.91–3.14 Å. In the second Tb site, Tb is bonded to six equivalent Br atoms to form edge-sharing TbBr6 octahedra. All Tb–Br bond lengths are 2.83 Å. Rh is bonded in an octahedral geometry to six equivalent Tb atoms. There are two inequivalent Br sites. In the first Br site, Br is bonded in a T-shaped geometry to three equivalent Tb atoms. In the second Br site, Br is bonded in a distorted T-shaped geometry to three Tb atoms.},
doi = {10.17188/1685740},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}