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Title: Materials Data on Tb7RhBr12 by Materials Project

Abstract

Tb7RhBr12 is trigonal omega-derived structured and crystallizes in the trigonal R-3 space group. The structure is three-dimensional. there are two inequivalent Tb sites. In the first Tb site, Tb is bonded to one Rh and five Br atoms to form a mixture of corner and edge-sharing TbRhBr5 octahedra. The corner-sharing octahedra tilt angles range from 0–3°. The Tb–Rh bond length is 2.68 Å. There are a spread of Tb–Br bond distances ranging from 2.91–3.14 Å. In the second Tb site, Tb is bonded to six equivalent Br atoms to form edge-sharing TbBr6 octahedra. All Tb–Br bond lengths are 2.83 Å. Rh is bonded in an octahedral geometry to six equivalent Tb atoms. There are two inequivalent Br sites. In the first Br site, Br is bonded in a T-shaped geometry to three equivalent Tb atoms. In the second Br site, Br is bonded in a distorted T-shaped geometry to three Tb atoms.

Publication Date:
Other Number(s):
mp-1189645
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Tb7RhBr12; Br-Rh-Tb
OSTI Identifier:
1685740
DOI:
https://doi.org/10.17188/1685740

Citation Formats

The Materials Project. Materials Data on Tb7RhBr12 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1685740.
The Materials Project. Materials Data on Tb7RhBr12 by Materials Project. United States. doi:https://doi.org/10.17188/1685740
The Materials Project. 2020. "Materials Data on Tb7RhBr12 by Materials Project". United States. doi:https://doi.org/10.17188/1685740. https://www.osti.gov/servlets/purl/1685740. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1685740,
title = {Materials Data on Tb7RhBr12 by Materials Project},
author = {The Materials Project},
abstractNote = {Tb7RhBr12 is trigonal omega-derived structured and crystallizes in the trigonal R-3 space group. The structure is three-dimensional. there are two inequivalent Tb sites. In the first Tb site, Tb is bonded to one Rh and five Br atoms to form a mixture of corner and edge-sharing TbRhBr5 octahedra. The corner-sharing octahedra tilt angles range from 0–3°. The Tb–Rh bond length is 2.68 Å. There are a spread of Tb–Br bond distances ranging from 2.91–3.14 Å. In the second Tb site, Tb is bonded to six equivalent Br atoms to form edge-sharing TbBr6 octahedra. All Tb–Br bond lengths are 2.83 Å. Rh is bonded in an octahedral geometry to six equivalent Tb atoms. There are two inequivalent Br sites. In the first Br site, Br is bonded in a T-shaped geometry to three equivalent Tb atoms. In the second Br site, Br is bonded in a distorted T-shaped geometry to three Tb atoms.},
doi = {10.17188/1685740},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}