U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Sr2MnSbO6 by Materials Project
Abstract
Sr2MnSbO6 crystallizes in the tetragonal I4/m space group. The structure is three-dimensional. Sr2+ is bonded in a 12-coordinate geometry to eight O2- atoms. There are four shorter (2.64 Å) and four longer (2.77 Å) Sr–O bond lengths. Mn3+ is bonded to six O2- atoms to form MnO6 octahedra that share corners with six equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 0–22°. There are four shorter (1.96 Å) and two longer (2.27 Å) Mn–O bond lengths. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with six equivalent MnO6 octahedra. The corner-sharing octahedra tilt angles range from 0–22°. There are two shorter (1.98 Å) and four longer (2.02 Å) Sb–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to four equivalent Sr2+, one Mn3+, and one Sb5+ atom to form a mixture of distorted corner and edge-sharing OSr4MnSb octahedra. The corner-sharing octahedra tilt angles range from 0–6°. In the second O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Sr2+, one Mn3+, and one Sb5+ atom.
- Publication Date:
- Other Number(s):
- mp-1218763
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Mn-O-Sb-Sr; Sr2MnSbO6; crystal structure
- OSTI Identifier:
- 1685200
- DOI:
- https://doi.org/10.17188/1685200
Citation Formats
Materials Data on Sr2MnSbO6 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1685200.
Materials Data on Sr2MnSbO6 by Materials Project. United States. doi:https://doi.org/10.17188/1685200
2020.
"Materials Data on Sr2MnSbO6 by Materials Project". United States. doi:https://doi.org/10.17188/1685200. https://www.osti.gov/servlets/purl/1685200. Pub date:Sun May 03 04:00:00 UTC 2020
@article{osti_1685200,
title = {Materials Data on Sr2MnSbO6 by Materials Project},
abstractNote = {Sr2MnSbO6 crystallizes in the tetragonal I4/m space group. The structure is three-dimensional. Sr2+ is bonded in a 12-coordinate geometry to eight O2- atoms. There are four shorter (2.64 Å) and four longer (2.77 Å) Sr–O bond lengths. Mn3+ is bonded to six O2- atoms to form MnO6 octahedra that share corners with six equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 0–22°. There are four shorter (1.96 Å) and two longer (2.27 Å) Mn–O bond lengths. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with six equivalent MnO6 octahedra. The corner-sharing octahedra tilt angles range from 0–22°. There are two shorter (1.98 Å) and four longer (2.02 Å) Sb–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to four equivalent Sr2+, one Mn3+, and one Sb5+ atom to form a mixture of distorted corner and edge-sharing OSr4MnSb octahedra. The corner-sharing octahedra tilt angles range from 0–6°. In the second O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Sr2+, one Mn3+, and one Sb5+ atom.},
doi = {10.17188/1685200},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}