U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on FeSO10 by Materials Project
Abstract
(FeSO5)2(O2)5 crystallizes in the trigonal R-3 space group. The structure is one-dimensional and consists of three hexaoxane molecules; thirty-six oxygen molecules; and six FeSO5 ribbons oriented in the (0, 0, 1) direction. In each FeSO5 ribbon, Fe is bonded to four O atoms to form FeO4 tetrahedra that share corners with two equivalent FeO4 tetrahedra and corners with two equivalent SO4 tetrahedra. There are a spread of Fe–O bond distances ranging from 1.83–1.95 Å. S is bonded to four O atoms to form SO4 tetrahedra that share corners with two equivalent FeO4 tetrahedra. There are a spread of S–O bond distances ranging from 1.45–1.53 Å. There are five inequivalent O sites. In the first O site, O is bonded in a bent 150 degrees geometry to one Fe and one S atom. In the second O site, O is bonded in a single-bond geometry to one S atom. In the third O site, O is bonded in a single-bond geometry to one S atom. In the fourth O site, O is bonded in a bent 120 degrees geometry to one Fe and one S atom. In the fifth O site, O is bonded in a bent 120 degrees geometry tomore »
- Publication Date:
- Other Number(s):
- mp-1199695
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Fe-O-S; FeSO10; crystal structure
- OSTI Identifier:
- 1685131
- DOI:
- https://doi.org/10.17188/1685131
Citation Formats
Materials Data on FeSO10 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1685131.
Materials Data on FeSO10 by Materials Project. United States. doi:https://doi.org/10.17188/1685131
2020.
"Materials Data on FeSO10 by Materials Project". United States. doi:https://doi.org/10.17188/1685131. https://www.osti.gov/servlets/purl/1685131. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1685131,
title = {Materials Data on FeSO10 by Materials Project},
abstractNote = {(FeSO5)2(O2)5 crystallizes in the trigonal R-3 space group. The structure is one-dimensional and consists of three hexaoxane molecules; thirty-six oxygen molecules; and six FeSO5 ribbons oriented in the (0, 0, 1) direction. In each FeSO5 ribbon, Fe is bonded to four O atoms to form FeO4 tetrahedra that share corners with two equivalent FeO4 tetrahedra and corners with two equivalent SO4 tetrahedra. There are a spread of Fe–O bond distances ranging from 1.83–1.95 Å. S is bonded to four O atoms to form SO4 tetrahedra that share corners with two equivalent FeO4 tetrahedra. There are a spread of S–O bond distances ranging from 1.45–1.53 Å. There are five inequivalent O sites. In the first O site, O is bonded in a bent 150 degrees geometry to one Fe and one S atom. In the second O site, O is bonded in a single-bond geometry to one S atom. In the third O site, O is bonded in a single-bond geometry to one S atom. In the fourth O site, O is bonded in a bent 120 degrees geometry to one Fe and one S atom. In the fifth O site, O is bonded in a bent 120 degrees geometry to two equivalent Fe atoms.},
doi = {10.17188/1685131},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}