U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on RbEu(WO4)2 by Materials Project
Abstract
RbEuW2O8 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Rb1+ is bonded in a 12-coordinate geometry to ten O2- atoms. There are a spread of Rb–O bond distances ranging from 2.95–3.14 Å. Eu3+ is bonded in a 6-coordinate geometry to eight O2- atoms. There are a spread of Eu–O bond distances ranging from 2.37–2.85 Å. W6+ is bonded to six O2- atoms to form a mixture of distorted edge and corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 42°. There are a spread of W–O bond distances ranging from 1.83–2.18 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Rb1+ and two equivalent W6+ atoms. In the second O2- site, O2- is bonded in a 2-coordinate geometry to one Rb1+, two equivalent Eu3+, and one W6+ atom. In the third O2- site, O2- is bonded in a 3-coordinate geometry to one Rb1+, one Eu3+, and two equivalent W6+ atoms. In the fourth O2- site, O2- is bonded in a 2-coordinate geometry to one Rb1+, one Eu3+, and one W6+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1209558
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; RbEu(WO4)2; Eu-O-Rb-W
- OSTI Identifier:
- 1683716
- DOI:
- https://doi.org/10.17188/1683716
Citation Formats
The Materials Project. Materials Data on RbEu(WO4)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1683716.
The Materials Project. Materials Data on RbEu(WO4)2 by Materials Project. United States. doi:https://doi.org/10.17188/1683716
The Materials Project. 2020.
"Materials Data on RbEu(WO4)2 by Materials Project". United States. doi:https://doi.org/10.17188/1683716. https://www.osti.gov/servlets/purl/1683716. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1683716,
title = {Materials Data on RbEu(WO4)2 by Materials Project},
author = {The Materials Project},
abstractNote = {RbEuW2O8 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Rb1+ is bonded in a 12-coordinate geometry to ten O2- atoms. There are a spread of Rb–O bond distances ranging from 2.95–3.14 Å. Eu3+ is bonded in a 6-coordinate geometry to eight O2- atoms. There are a spread of Eu–O bond distances ranging from 2.37–2.85 Å. W6+ is bonded to six O2- atoms to form a mixture of distorted edge and corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 42°. There are a spread of W–O bond distances ranging from 1.83–2.18 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Rb1+ and two equivalent W6+ atoms. In the second O2- site, O2- is bonded in a 2-coordinate geometry to one Rb1+, two equivalent Eu3+, and one W6+ atom. In the third O2- site, O2- is bonded in a 3-coordinate geometry to one Rb1+, one Eu3+, and two equivalent W6+ atoms. In the fourth O2- site, O2- is bonded in a 2-coordinate geometry to one Rb1+, one Eu3+, and one W6+ atom.},
doi = {10.17188/1683716},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}