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Title: Materials Data on CeSi3Rh by Materials Project

Abstract

CeRhSi3 crystallizes in the tetragonal I4mm space group. The structure is three-dimensional. Ce is bonded in a 12-coordinate geometry to five equivalent Rh and twelve Si atoms. There are one shorter (3.34 Å) and four longer (3.37 Å) Ce–Rh bond lengths. There are eight shorter (3.10 Å) and four longer (3.37 Å) Ce–Si bond lengths. Rh is bonded in a 5-coordinate geometry to five equivalent Ce and five Si atoms. There are one shorter (2.36 Å) and four longer (2.37 Å) Rh–Si bond lengths. There are two inequivalent Si sites. In the first Si site, Si is bonded in a distorted single-bond geometry to four equivalent Ce, one Rh, and four equivalent Si atoms. All Si–Si bond lengths are 2.57 Å. In the second Si site, Si is bonded in a distorted bent 120 degrees geometry to four equivalent Ce, two equivalent Rh, and two equivalent Si atoms.

Authors:
Publication Date:
Other Number(s):
mp-1070394
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; CeSi3Rh; Ce-Rh-Si
OSTI Identifier:
1683687
DOI:
https://doi.org/10.17188/1683687

Citation Formats

The Materials Project. Materials Data on CeSi3Rh by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1683687.
The Materials Project. Materials Data on CeSi3Rh by Materials Project. United States. doi:https://doi.org/10.17188/1683687
The Materials Project. 2020. "Materials Data on CeSi3Rh by Materials Project". United States. doi:https://doi.org/10.17188/1683687. https://www.osti.gov/servlets/purl/1683687. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1683687,
title = {Materials Data on CeSi3Rh by Materials Project},
author = {The Materials Project},
abstractNote = {CeRhSi3 crystallizes in the tetragonal I4mm space group. The structure is three-dimensional. Ce is bonded in a 12-coordinate geometry to five equivalent Rh and twelve Si atoms. There are one shorter (3.34 Å) and four longer (3.37 Å) Ce–Rh bond lengths. There are eight shorter (3.10 Å) and four longer (3.37 Å) Ce–Si bond lengths. Rh is bonded in a 5-coordinate geometry to five equivalent Ce and five Si atoms. There are one shorter (2.36 Å) and four longer (2.37 Å) Rh–Si bond lengths. There are two inequivalent Si sites. In the first Si site, Si is bonded in a distorted single-bond geometry to four equivalent Ce, one Rh, and four equivalent Si atoms. All Si–Si bond lengths are 2.57 Å. In the second Si site, Si is bonded in a distorted bent 120 degrees geometry to four equivalent Ce, two equivalent Rh, and two equivalent Si atoms.},
doi = {10.17188/1683687},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}