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Title: Materials Data on Hg3RhF6 by Materials Project

Abstract

RhHg2F4HgF2 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one mercuric fluoride molecule and one RhHg2F4 sheet oriented in the (0, 0, 1) direction. In the RhHg2F4 sheet, Rh3+ is bonded in a square co-planar geometry to four F1- atoms. There is two shorter (1.90 Å) and two longer (1.91 Å) Rh–F bond length. There are two inequivalent Hg1+ sites. In the first Hg1+ site, Hg1+ is bonded in a distorted linear geometry to two equivalent F1- atoms. Both Hg–F bond lengths are 2.95 Å. In the second Hg1+ site, Hg1+ is bonded in a linear geometry to two equivalent F1- atoms. Both Hg–F bond lengths are 2.77 Å. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 120 degrees geometry to one Rh3+ and one Hg1+ atom. In the second F1- site, F1- is bonded in a 1-coordinate geometry to one Rh3+ and one Hg1+ atom.

Authors:
Publication Date:
Other Number(s):
mp-1213284
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Hg3RhF6; F-Hg-Rh
OSTI Identifier:
1682733
DOI:
https://doi.org/10.17188/1682733

Citation Formats

The Materials Project. Materials Data on Hg3RhF6 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1682733.
The Materials Project. Materials Data on Hg3RhF6 by Materials Project. United States. doi:https://doi.org/10.17188/1682733
The Materials Project. 2019. "Materials Data on Hg3RhF6 by Materials Project". United States. doi:https://doi.org/10.17188/1682733. https://www.osti.gov/servlets/purl/1682733. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1682733,
title = {Materials Data on Hg3RhF6 by Materials Project},
author = {The Materials Project},
abstractNote = {RhHg2F4HgF2 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one mercuric fluoride molecule and one RhHg2F4 sheet oriented in the (0, 0, 1) direction. In the RhHg2F4 sheet, Rh3+ is bonded in a square co-planar geometry to four F1- atoms. There is two shorter (1.90 Å) and two longer (1.91 Å) Rh–F bond length. There are two inequivalent Hg1+ sites. In the first Hg1+ site, Hg1+ is bonded in a distorted linear geometry to two equivalent F1- atoms. Both Hg–F bond lengths are 2.95 Å. In the second Hg1+ site, Hg1+ is bonded in a linear geometry to two equivalent F1- atoms. Both Hg–F bond lengths are 2.77 Å. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 120 degrees geometry to one Rh3+ and one Hg1+ atom. In the second F1- site, F1- is bonded in a 1-coordinate geometry to one Rh3+ and one Hg1+ atom.},
doi = {10.17188/1682733},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}