U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on YSb(PbO3)2 by Materials Project
Abstract
YSb(PbO3)2 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Y3+ is bonded to six O2- atoms to form YO6 octahedra that share corners with six equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 21–25°. There are two shorter (2.25 Å) and four longer (2.27 Å) Y–O bond lengths. Pb2+ is bonded in a 9-coordinate geometry to five O2- atoms. There are a spread of Pb–O bond distances ranging from 2.61–2.68 Å. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with six equivalent YO6 octahedra. The corner-sharing octahedra tilt angles range from 21–25°. There are two shorter (2.01 Å) and four longer (2.02 Å) Sb–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 2-coordinate geometry to one Y3+, two equivalent Pb2+, and one Sb5+ atom. In the second O2- site, O2- is bonded in a 2-coordinate geometry to one Y3+, one Pb2+, and one Sb5+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1078392
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; YSb(PbO3)2; O-Pb-Sb-Y
- OSTI Identifier:
- 1681229
- DOI:
- https://doi.org/10.17188/1681229
Citation Formats
The Materials Project. Materials Data on YSb(PbO3)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1681229.
The Materials Project. Materials Data on YSb(PbO3)2 by Materials Project. United States. doi:https://doi.org/10.17188/1681229
The Materials Project. 2020.
"Materials Data on YSb(PbO3)2 by Materials Project". United States. doi:https://doi.org/10.17188/1681229. https://www.osti.gov/servlets/purl/1681229. Pub date:Mon May 04 00:00:00 EDT 2020
@article{osti_1681229,
title = {Materials Data on YSb(PbO3)2 by Materials Project},
author = {The Materials Project},
abstractNote = {YSb(PbO3)2 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Y3+ is bonded to six O2- atoms to form YO6 octahedra that share corners with six equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 21–25°. There are two shorter (2.25 Å) and four longer (2.27 Å) Y–O bond lengths. Pb2+ is bonded in a 9-coordinate geometry to five O2- atoms. There are a spread of Pb–O bond distances ranging from 2.61–2.68 Å. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with six equivalent YO6 octahedra. The corner-sharing octahedra tilt angles range from 21–25°. There are two shorter (2.01 Å) and four longer (2.02 Å) Sb–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 2-coordinate geometry to one Y3+, two equivalent Pb2+, and one Sb5+ atom. In the second O2- site, O2- is bonded in a 2-coordinate geometry to one Y3+, one Pb2+, and one Sb5+ atom.},
doi = {10.17188/1681229},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}